{"title":"竹饰面多协同阻燃水凝胶涂料","authors":"Haomeng Yu , Zewei Ye , Zhihao Yue, Shitao Shi, Yuanyuan Wang, Jiaqi Liao, Wenwen Zhu, Chencong Liu, Bo Chen, Qingfeng Sun, Xiaoping Shen","doi":"10.1016/j.indcrop.2024.120324","DOIUrl":null,"url":null,"abstract":"<div><div>The urgent demand for fire-safe coatings in bamboo furniture has driven significant progress in developing halogen-free flame-retardant technologies. This study presents a new multi-synergistic flame-retardant hydrogel coating, composed of methylcellulose (MC), polyacrylamide (PAAm), and tetraethyl orthosilicate (TEOS)-pretreated ammonium polyphosphate (SiO<sub>2</sub>@APP) for bamboo veneers. The uniformly dispersed SiO<sub>2</sub>@APP serves as an acid catalyst and an incombustible gas source, while MC and PAAm act as carbon sources in the fire-resistant C-Si-P-N coating system. Additionally, the hydrogel containing MC and water provides significant heat absorption, improving its flame-retardant efficacy. The limiting oxygen index (LOI) of the resultant hydrogel-coated bamboo (HB) increases significantly from 22.1 % to 55.9 %. Notable reductions of 20.3 % and 53.1 % in the peak heat release rate (PHRR) and total heat release (THR) of the hydrogel-coated bamboo (HB) are observed, respectively, in comparison to the original bamboo. After combustion, the dense hybrid char layer incorporating P, N, and Si effectively impedes heat release and combustible gas diffusion. Additionally, the hydrogel coating exhibits excellent interfacial adhesive strength (125.9 kPa) on the bamboo surface. Through this simple and facile sol-gel preparation process, efficient flame-retardant coatings demonstrate promising potential for biomass-based materials in diverse applications, including furniture, commercial buildings, and industrial uses.</div></div>","PeriodicalId":13581,"journal":{"name":"Industrial Crops and Products","volume":"224 ","pages":"Article 120324"},"PeriodicalIF":5.6000,"publicationDate":"2025-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Multi-synergistic flame-retardant hydrogel coating for bamboo veneers\",\"authors\":\"Haomeng Yu , Zewei Ye , Zhihao Yue, Shitao Shi, Yuanyuan Wang, Jiaqi Liao, Wenwen Zhu, Chencong Liu, Bo Chen, Qingfeng Sun, Xiaoping Shen\",\"doi\":\"10.1016/j.indcrop.2024.120324\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>The urgent demand for fire-safe coatings in bamboo furniture has driven significant progress in developing halogen-free flame-retardant technologies. This study presents a new multi-synergistic flame-retardant hydrogel coating, composed of methylcellulose (MC), polyacrylamide (PAAm), and tetraethyl orthosilicate (TEOS)-pretreated ammonium polyphosphate (SiO<sub>2</sub>@APP) for bamboo veneers. The uniformly dispersed SiO<sub>2</sub>@APP serves as an acid catalyst and an incombustible gas source, while MC and PAAm act as carbon sources in the fire-resistant C-Si-P-N coating system. Additionally, the hydrogel containing MC and water provides significant heat absorption, improving its flame-retardant efficacy. The limiting oxygen index (LOI) of the resultant hydrogel-coated bamboo (HB) increases significantly from 22.1 % to 55.9 %. Notable reductions of 20.3 % and 53.1 % in the peak heat release rate (PHRR) and total heat release (THR) of the hydrogel-coated bamboo (HB) are observed, respectively, in comparison to the original bamboo. After combustion, the dense hybrid char layer incorporating P, N, and Si effectively impedes heat release and combustible gas diffusion. Additionally, the hydrogel coating exhibits excellent interfacial adhesive strength (125.9 kPa) on the bamboo surface. 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引用次数: 0
摘要
竹制家具对防火涂料的迫切需求推动了无卤阻燃技术的发展。本研究提出了一种新型多元协同阻燃水凝胶涂料,由甲基纤维素(MC)、聚丙烯酰胺(PAAm)和经正硅酸四乙酯(TEOS)处理的聚磷酸铵(SiO2@APP)组成,适用于竹单板。均匀分散的 SiO2@APP 可作为酸催化剂和不可燃气体源,而 MC 和 PAAm 可作为耐火 C-Si-P-N 涂层系统中的碳源。此外,含有 MC 和水的水凝胶具有显著的吸热性,从而提高了阻燃效果。水凝胶涂层竹材(HB)的极限氧指数(LOI)从 22.1% 显著提高到 55.9%。与原始竹材相比,水凝胶涂层竹材(HB)的峰值放热率(PHRR)和总放热率(THR)分别显著降低了 20.3% 和 53.1%。燃烧后,含有 P、N 和 Si 的致密混合炭层有效地阻碍了热量的释放和可燃气体的扩散。此外,水凝胶涂层在竹材表面表现出优异的界面粘附强度(125.9 kPa)。通过这种简单易行的溶胶-凝胶制备工艺,高效阻燃涂层展示了生物质材料在家具、商业建筑和工业用途等多种应用中的巨大潜力。
Multi-synergistic flame-retardant hydrogel coating for bamboo veneers
The urgent demand for fire-safe coatings in bamboo furniture has driven significant progress in developing halogen-free flame-retardant technologies. This study presents a new multi-synergistic flame-retardant hydrogel coating, composed of methylcellulose (MC), polyacrylamide (PAAm), and tetraethyl orthosilicate (TEOS)-pretreated ammonium polyphosphate (SiO2@APP) for bamboo veneers. The uniformly dispersed SiO2@APP serves as an acid catalyst and an incombustible gas source, while MC and PAAm act as carbon sources in the fire-resistant C-Si-P-N coating system. Additionally, the hydrogel containing MC and water provides significant heat absorption, improving its flame-retardant efficacy. The limiting oxygen index (LOI) of the resultant hydrogel-coated bamboo (HB) increases significantly from 22.1 % to 55.9 %. Notable reductions of 20.3 % and 53.1 % in the peak heat release rate (PHRR) and total heat release (THR) of the hydrogel-coated bamboo (HB) are observed, respectively, in comparison to the original bamboo. After combustion, the dense hybrid char layer incorporating P, N, and Si effectively impedes heat release and combustible gas diffusion. Additionally, the hydrogel coating exhibits excellent interfacial adhesive strength (125.9 kPa) on the bamboo surface. Through this simple and facile sol-gel preparation process, efficient flame-retardant coatings demonstrate promising potential for biomass-based materials in diverse applications, including furniture, commercial buildings, and industrial uses.
期刊介绍:
Industrial Crops and Products is an International Journal publishing academic and industrial research on industrial (defined as non-food/non-feed) crops and products. Papers concern both crop-oriented and bio-based materials from crops-oriented research, and should be of interest to an international audience, hypothesis driven, and where comparisons are made statistics performed.