借氢锰催化下酮和仲醇的三戊基化反应

IF 3.3 2区化学 Q1 CHEMISTRY, ORGANIC

Journal of Organic Chemistry Pub Date : 2024-12-16 DOI:10.1021/acs.joc.4c02260

Sachin Jalwal, Sourajit Das, Subrata Chakraborty

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Terpenylation of Ketones and a Secondary Alcohol under Hydrogen-Borrowing Manganese Catalysis

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Terpenylation of Ketones and a Secondary Alcohol under Hydrogen-Borrowing Manganese Catalysis

An Earth-abundant Mn–PNP pincer complex-catalyzed terpenylation of cyclic and acyclic ketones and secondary alcohol 1-phenylethanol using isoprenoid derivatives prenol, nerol, phytol, solanesol, and E-farnesol as allyl surrogates is reported. The C–C coupling reactions are green and atom-economic, proceeding via dehydrogenation of alcohols following a hydrogen autotransfer methodology aided by metal–ligand cooperation.

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来源期刊

Journal of Organic Chemistry 化学-有机化学

CiteScore

6.20

自引率

11.10%

发文量

1467

审稿时长

2 months

期刊介绍： Journal of Organic Chemistry welcomes original contributions of fundamental research in all branches of the theory and practice of organic chemistry. In selecting manuscripts for publication, the editors place emphasis on the quality and novelty of the work, as well as the breadth of interest to the organic chemistry community.