使用 Pd/Et3SiH 试剂系统氢化糖烯醚:脱氧糖/糖苷的途径

IF 3.6 2区 化学 Q1 CHEMISTRY, ORGANIC
Bindu Tiwari, Ram Pratap Pandey, Nazar Hussain
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引用次数: 0

摘要

以Pd(OAc)2/Et3SiH为试剂体系,建立了糖烯醇醚及其糖苷的加氢方法。该方法非常有效,适用于广泛的甘糖和糖苷,相应的脱氧糖的产率高达96%。在标准条件下,各种O/ c糖苷转化为2,3-二脱氧糖苷的效果良好。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Hydrogenation of Sugar Enol-Ethers Using Pd/Et3SiH Reagent System: A Route to Deoxy Sugars/Glycosides

Hydrogenation of Sugar Enol-Ethers Using Pd/Et3SiH Reagent System: A Route to Deoxy Sugars/Glycosides
We have developed a hydrogenation method using Pd(OAc)2/Et3SiH as a reagent system for sugar enol ethers and their glycosides. This approach is highly effective and applicable to a wide range of glycals and glycosides, achieving yields up to 96% for the corresponding deoxy sugars. Applying standard conditions to various O/C-glycosides resulted in excellent transformation to 2,3-dideoxy glycosides.
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来源期刊
Journal of Organic Chemistry
Journal of Organic Chemistry 化学-有机化学
CiteScore
6.20
自引率
11.10%
发文量
1467
审稿时长
2 months
期刊介绍: Journal of Organic Chemistry welcomes original contributions of fundamental research in all branches of the theory and practice of organic chemistry. In selecting manuscripts for publication, the editors place emphasis on the quality and novelty of the work, as well as the breadth of interest to the organic chemistry community.
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