IF 16.1 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY
Haohui Hu, Wei Jiang, Xiao Han, Geng Wu, Haoran Wang, Yi Shi, Dayin He, Xianhui Ma, Xun Hong
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引用次数: 0

摘要

将纳米材料自组装成分层结构是制造功能材料的重要方法。然而,组装结构的可编程设计仍然是一个巨大的挑战。在此,我们报告了一种可编程自组装策略,以定制组装结构。该自组装策略旨在将二维(2D)钙离子组装的F127纳米片(Ca-F127 NSs)有序转化为螺旋纳米片结构(S-Ca-F127 NSs)、支化纳米片结构(B-Ca-F127 NSs)、支化螺旋纳米片结构(B-S-Ca-F127 NSs)和扭曲支化结构(T-Ca-F127 NBs)。广角 X 射线散射(WAXS)和 X 射线吸收光谱(XAS)表明,这些不同的结构保持了相同的正交相和 Ca-O 八面体配位结构。在双倾斜液氮冷却支架中进行的选区电子衍射(SAED)确定了扭曲结构中的埃舍尔比扭曲,证明螺旋结构是由螺旋位错生长形成的。低温电子显微镜(cryo-EM)证明了 B-Ca-F127 NSs 的定向外延生长。此外,螺旋结构和支化结构的形成机制可以重新组合,形成复杂的层次结构。沿螺旋位错的外延生长可导致 B-S-Ca-F127 NSs 的形成,而螺旋位错中的扭曲外延生长可导致 T-Ca F127 NBs 的形成。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Programmable Self-assembly from Two-dimensional Nanosheets to Spiral, Twisted and Branched Nanostructures
Self-assembly of nanomaterials into hierarchical structure is of great interest to fabricate functional materials. However, programmable design of the assembled structures remains a great challenge. Herein, we reported a programmable self-assembly strategy to customize the assembled structure. The self-assembly strategy is designed to orderly transform the two-dimensional (2D) Ca ions assembled F127 nanosheets (Ca-F127 NSs) into spiral nanosheet structures (S-Ca-F127 NSs), branched nanosheet structures (B-Ca-F127 NSs), branched-spiral nanosheet structures (B-S-Ca-F127 NSs), and twisted-branched structures (T-Ca-F127 NBs). Wide-angle X-ray scattering (WAXS) and X-ray absorption spectroscopy (XAS) indicate that these different structures maintain the same orthorhombic phase and Ca-O octahedral coordination structure. Selected area electron diffraction (SAED) in the double-tilt liquid nitrogen cooling holder identifies the Eshelby twist in the twisted structures, demonstrating the spiral structure are formed by screw dislocation growth. Cryo-electron microscopy (cryo-EM) proves the oriented epitaxial growth in the B-Ca-F127 NSs. Furthermore, the formation mechanisms of spiral structure and branched structure can be recombined to form complex hierarchical structures. The epitaxial growth along screw dislocation can lead to the formation of B-S-Ca-F127 NSs, while the twisted epitaxial growth in the screw dislocation can lead to the formation of T-Ca F127 NBs.
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来源期刊
CiteScore
26.60
自引率
6.60%
发文量
3549
审稿时长
1.5 months
期刊介绍: Angewandte Chemie, a journal of the German Chemical Society (GDCh), maintains a leading position among scholarly journals in general chemistry with an impressive Impact Factor of 16.6 (2022 Journal Citation Reports, Clarivate, 2023). Published weekly in a reader-friendly format, it features new articles almost every day. Established in 1887, Angewandte Chemie is a prominent chemistry journal, offering a dynamic blend of Review-type articles, Highlights, Communications, and Research Articles on a weekly basis, making it unique in the field.
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