{"title":"低蒸发焓离子共价有机框架在低湿度条件下实现高效大气集水","authors":"Zheng Shi, Yu Guo, Xiuyang Zou, Jiamin Zhang, Zhiwei Chen, Mingqing Shan, Zhixin Zhang, Siyu Guo, Feng Yan","doi":"10.1002/anie.202420619","DOIUrl":null,"url":null,"abstract":"Herein, we introduce a series of ionic covalent organic frameworks (iCOFs) with a focus on addressing the challenge of water collection at low relative humidity levels below 25%. These iCOFs are characterized by numerous hydrophilic sites and high water stability, enabling efficient water vapor adsorption even at relatively low humidity levels. Through the use of various hygroscopic salt cations and precise control of ion concentration within the pores, the water state within the iCOFs pores can be effectively managed. Among the iCOFs, TB-COF-Li stands out with an impressive adsorption capacity of 0.24 g g-1 from 0 to 22% RH. Notably, due to its ionic porous structure, TB-COF-Li exhibits a significantly lower enthalpy of evaporation, measured at 967.04 J g-1, compared to bulk water with an enthalpy of 2387.4 J g-1. Moreover, under simulated conditions of 1.5 solar intensity at 60 °C, the majority of the adsorbed water can be rapidly desorbed without the need for additional energy input. This efficient desorption process contributes to a high water collection rate of 0.092 g g-1 h-1 in the final atmospheric water harvesting device. The development of these iCOFs offers a promising and cost-effective solution for obtaining fresh water in arid regions.","PeriodicalId":125,"journal":{"name":"Angewandte Chemie International Edition","volume":"25 1","pages":""},"PeriodicalIF":16.1000,"publicationDate":"2024-12-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Low Evaporation Enthalpy Ionic Covalent Organic Frameworks for Efficient Atmospheric Water Harvesting at Low Humidity\",\"authors\":\"Zheng Shi, Yu Guo, Xiuyang Zou, Jiamin Zhang, Zhiwei Chen, Mingqing Shan, Zhixin Zhang, Siyu Guo, Feng Yan\",\"doi\":\"10.1002/anie.202420619\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Herein, we introduce a series of ionic covalent organic frameworks (iCOFs) with a focus on addressing the challenge of water collection at low relative humidity levels below 25%. These iCOFs are characterized by numerous hydrophilic sites and high water stability, enabling efficient water vapor adsorption even at relatively low humidity levels. Through the use of various hygroscopic salt cations and precise control of ion concentration within the pores, the water state within the iCOFs pores can be effectively managed. Among the iCOFs, TB-COF-Li stands out with an impressive adsorption capacity of 0.24 g g-1 from 0 to 22% RH. Notably, due to its ionic porous structure, TB-COF-Li exhibits a significantly lower enthalpy of evaporation, measured at 967.04 J g-1, compared to bulk water with an enthalpy of 2387.4 J g-1. Moreover, under simulated conditions of 1.5 solar intensity at 60 °C, the majority of the adsorbed water can be rapidly desorbed without the need for additional energy input. This efficient desorption process contributes to a high water collection rate of 0.092 g g-1 h-1 in the final atmospheric water harvesting device. The development of these iCOFs offers a promising and cost-effective solution for obtaining fresh water in arid regions.\",\"PeriodicalId\":125,\"journal\":{\"name\":\"Angewandte Chemie International Edition\",\"volume\":\"25 1\",\"pages\":\"\"},\"PeriodicalIF\":16.1000,\"publicationDate\":\"2024-12-16\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Angewandte Chemie International Edition\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1002/anie.202420619\",\"RegionNum\":1,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Angewandte Chemie International Edition","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1002/anie.202420619","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Low Evaporation Enthalpy Ionic Covalent Organic Frameworks for Efficient Atmospheric Water Harvesting at Low Humidity
Herein, we introduce a series of ionic covalent organic frameworks (iCOFs) with a focus on addressing the challenge of water collection at low relative humidity levels below 25%. These iCOFs are characterized by numerous hydrophilic sites and high water stability, enabling efficient water vapor adsorption even at relatively low humidity levels. Through the use of various hygroscopic salt cations and precise control of ion concentration within the pores, the water state within the iCOFs pores can be effectively managed. Among the iCOFs, TB-COF-Li stands out with an impressive adsorption capacity of 0.24 g g-1 from 0 to 22% RH. Notably, due to its ionic porous structure, TB-COF-Li exhibits a significantly lower enthalpy of evaporation, measured at 967.04 J g-1, compared to bulk water with an enthalpy of 2387.4 J g-1. Moreover, under simulated conditions of 1.5 solar intensity at 60 °C, the majority of the adsorbed water can be rapidly desorbed without the need for additional energy input. This efficient desorption process contributes to a high water collection rate of 0.092 g g-1 h-1 in the final atmospheric water harvesting device. The development of these iCOFs offers a promising and cost-effective solution for obtaining fresh water in arid regions.
期刊介绍:
Angewandte Chemie, a journal of the German Chemical Society (GDCh), maintains a leading position among scholarly journals in general chemistry with an impressive Impact Factor of 16.6 (2022 Journal Citation Reports, Clarivate, 2023). Published weekly in a reader-friendly format, it features new articles almost every day. Established in 1887, Angewandte Chemie is a prominent chemistry journal, offering a dynamic blend of Review-type articles, Highlights, Communications, and Research Articles on a weekly basis, making it unique in the field.