Na Wang, Huli Yu, Hai Zhong, Min Duan, Biao Zhao, Jianping Deng
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引用次数: 0
摘要
具有圆偏振发光(CPL)特性的有机发光二极管因其在 3D 显示、自旋电子学、加密数据存储等方面的巨大潜力而受到广泛关注。在已报道的各种 CPL 材料中,聚合物基手性发射极因其热稳定性高、成膜性好、成本低和溶液加工性好等优点,已成为一类重要的材料,有助于开发发射颜色可调、大面积和灵活的光电器件。在这篇综述中,我们系统地总结了圆偏振聚合物发光二极管(CP-PLED)的最新研究成果,介绍了不同类型的聚合物基发光材料,包括手性共轭发光聚合物、掺杂手性诱导剂的非手性共轭发光聚合物以及手性聚合物基金属复合物。此外,文章还讨论了 CP-PLED 未来发展所面临的挑战和机遇。这篇综述文章有望推动聚合物基 CPL 发光体以及相关电致发光器件取得更多前所未有的成就,从而进一步促进其未来的实际应用。
Circularly polarized polymeric light-emitting diodes: preparation and properties
Organic light emitting diodes with circularly polarized luminescence (CPL) properties have drawn extensive attention owing to their significant potentials in 3D displays, spintronics, encrypted data storage, and so forth. Amongst various reported CPL materials, polymer-based chiral emitters have constituted an important class because of their advantages of high thermal stability, good film-forming property, low cost and good solution processability, which are helpful in developing emission-color adjustable, large area and flexible photoelectric devices. In this review, we systematically summarize the state-of-the-art of circularly polarized polymeric light-emitting diodes (CP-PLEDs), in which the different types of polymer-based emitting materials covering chiral conjugated luminescent polymers, achiral conjugated luminescent polymers doped with chiral inducers, and chiral polymer-based metal complexes are introduced. Additionally, the challenges and opportunities for the future development of CP-PLEDs are also discussed. This review article is expected to stimulate more unprecedented achievements of polymer-based CPL emitters as well as the related electroluminescent devices, thus further promoting their future practical applications.
期刊介绍:
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.