ZnO-TA 纳米吸附剂用于萃取铀(vi)和钍(iv)的再固定化:通过方框-贝肯设计模型进行吸附优化†。

IF 2.7 3区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY
Manish Sharma, Priya Sharma, Payal Taneja, Vikash Chandra Janu and Ragini Gupta
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引用次数: 0

摘要

核技术的迅速发展导致放射性废水量不断增加,对环境造成威胁,因此必须清除污染物以保护环境。本报告介绍了利用高效 ZnO-TA 纳米吸附剂的吸附技术,通过离子与吸附剂表面活性官能团的相互作用,实现对铀(VI)和钍(IV)离子的封存。这种纳米吸附剂采用水热法成功合成,并通过各种分析技术进行了结构分析。批量实验研究了不同参数,如 pH 值、吸附剂用量、时间、吸附剂初始浓度和其他离子干扰的影响。通过响应面方法和系统批量研究对吸附研究参数进行了优化。在 pH =4 的条件下,使用 10 mL 50 mg L-1 的吸附剂浓度和 3 mg 和 4 mg 的吸附剂,在 15 分钟内分别获得了 99.98% (U(VI))和 98.80% (Th(IV))的最高离子去除率。此外,在最佳条件下,U(VI) 和 Th(IV) 离子的最大吸附容量分别为 909.09 mg g-1 和 380.62 mg g-1。这些结果是根据假二阶动力学的 Langmuir 等温线模型得出的。ZnO-TA纳米吸附剂对U(VI)和Th(IV)离子的吸附机理主要是通过静电作用和官能团活性结合位点之间的氢键相互作用来解释的。因此,研究结果表明,合成的吸附剂具有良好的可回收性,能有效吸附铀和钍。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Remobilization of ZnO–TA nanoadsorbent for U(vi) and Th(iv) extraction: adsorption optimization through the Box–Behnken design model†

Remobilization of ZnO–TA nanoadsorbent for U(vi) and Th(iv) extraction: adsorption optimization through the Box–Behnken design model†

The rapid expansion of nuclear technology has led to increasing volumes of radioactive wastewater, threatening the environment and necessitating the removal of contaminants in order to protect the surroundings. This report presents the sequestration of U(VI) and Th(IV) ions through an adsorption technique using a highly efficient ZnO–TA nanoadsorbent, driven by ionic interactions with the surface-active functional groups of the adsorbent. This nanoadsorbent was successfully synthesized using a hydrothermal process and structurally analyzed through various analytical techniques. Batch experiments were performed to study different parameters such as the influence of pH, amount of sorbent, time, initial concentration of sorbate, and interference of other ions. Adsorption study parameters were optimized via the response surface methodology and systematic batch studies. The highest removal efficiencies of 99.98% (U(VI)) and 98.80% (Th(IV)) ions were obtained at pH =4, using 10 mL of 50 mg L−1 adsorbate concentration with 3 mg and 4 mg of adsorbent within 15 min, respectively. Moreover, the maximum adsorption capacities under optimum conditions were evaluated to be 909.09 mg g−1 and 380.62 mg g−1 for U(VI) and Th(IV) ions, respectively. These results were derived using the Langmuir isotherm model adhering to pseudo-second-order kinetics. The dominant adsorption mechanism of U(VI) and Th(IV) onto the ZnO–TA nanoadsorbent is explained through the interplay of electrostatic interactions and hydrogen bonding between the functional group active binding sites. Therefore, the results stated that the synthesized adsorbent, with its excellent recyclability, is effective in uranium and thorium uptake.

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来源期刊
New Journal of Chemistry
New Journal of Chemistry 化学-化学综合
CiteScore
5.30
自引率
6.10%
发文量
1832
审稿时长
2 months
期刊介绍: A journal for new directions in chemistry
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