{"title":"一种铁电螺旋聚合物","authors":"Supriya Bandyopadhyay, Shubhankar Barman, Swadesh Paul, Anuja Datta, Suhrit Ghosh","doi":"10.1039/d4cc05250a","DOIUrl":null,"url":null,"abstract":"This communication introduces helical polyacetylene (P1) with an appended acceptor (A)–donor (D)–acceptor (A) conjugated chromophore as a promising ferroelectric candidate. The helical conformation of P1 leads to a highly stable chiral assembly of the appended ADA chromophores. This results in prominent ferroelectricity as evident from the superior hysteresis loop at room temperature, exhibiting a saturation polarization (<em>P</em><small><sub>S</sub></small>) value ∼2 μC cm<small><sup>−2</sup></small> and remanent polarization (<em>P</em><small><sub>r</sub></small>) value ∼1.8 μC cm<small><sup>−2</sup></small> at a low coercive field (<em>E</em><small><sub>c</sub></small>) of 5.2 kV cm<small><sup>−1</sup></small>, rarely reported before for purely organic systems.","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":"21 1","pages":""},"PeriodicalIF":4.3000,"publicationDate":"2024-12-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"A ferroelectric helical polymer\",\"authors\":\"Supriya Bandyopadhyay, Shubhankar Barman, Swadesh Paul, Anuja Datta, Suhrit Ghosh\",\"doi\":\"10.1039/d4cc05250a\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"This communication introduces helical polyacetylene (P1) with an appended acceptor (A)–donor (D)–acceptor (A) conjugated chromophore as a promising ferroelectric candidate. The helical conformation of P1 leads to a highly stable chiral assembly of the appended ADA chromophores. This results in prominent ferroelectricity as evident from the superior hysteresis loop at room temperature, exhibiting a saturation polarization (<em>P</em><small><sub>S</sub></small>) value ∼2 μC cm<small><sup>−2</sup></small> and remanent polarization (<em>P</em><small><sub>r</sub></small>) value ∼1.8 μC cm<small><sup>−2</sup></small> at a low coercive field (<em>E</em><small><sub>c</sub></small>) of 5.2 kV cm<small><sup>−1</sup></small>, rarely reported before for purely organic systems.\",\"PeriodicalId\":67,\"journal\":{\"name\":\"Chemical Communications\",\"volume\":\"21 1\",\"pages\":\"\"},\"PeriodicalIF\":4.3000,\"publicationDate\":\"2024-12-16\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chemical Communications\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1039/d4cc05250a\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemical Communications","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1039/d4cc05250a","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
This communication introduces helical polyacetylene (P1) with an appended acceptor (A)–donor (D)–acceptor (A) conjugated chromophore as a promising ferroelectric candidate. The helical conformation of P1 leads to a highly stable chiral assembly of the appended ADA chromophores. This results in prominent ferroelectricity as evident from the superior hysteresis loop at room temperature, exhibiting a saturation polarization (PS) value ∼2 μC cm−2 and remanent polarization (Pr) value ∼1.8 μC cm−2 at a low coercive field (Ec) of 5.2 kV cm−1, rarely reported before for purely organic systems.
期刊介绍:
ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.