Wahab Abdul, Christiane Rößler, Holger Kletti, Chancel Mawalala, Alexander Pisch, Marcus N. Bannerman, Theodore Hanein
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On the variability of industrial Portland cement clinker: Microstructural characterisation and the fate of chemical elements
Portland cement (PC) has been used and developed since the early 19th century. Although the compositional ranges of PC clinkers are generally specified in standards, there is a lack of information on the variability of industrial clinkers. Furthermore, with an increase in the use of alternative mineral and fuel feeds, it is important to understand the evolution of clinker chemistry and mineralogy which affects hydraulic reactivity. In this work, 27 clinkers, selected to span the limits of clinker manufacturing, are characterised using X-Ray fluorescence (XRF), X-Ray diffraction (XRD), and scanning electron microscopy - energy dispersive X-ray spectroscopy (SEM-EDX). These are compared against clinker data from literature, which provides a comparison between modern clinkers and historical clinkers analysed over 50 years ago. Finally, the clinker datasets are used to carry out and compare different calculation methods including Bogue, modified Bogue, and Gibbs energy minimisation using a published stoichiometric thermodynamic database.
期刊介绍:
Cement and Concrete Research is dedicated to publishing top-notch research on the materials science and engineering of cement, cement composites, mortars, concrete, and related materials incorporating cement or other mineral binders. The journal prioritizes reporting significant findings in research on the properties and performance of cementitious materials. It also covers novel experimental techniques, the latest analytical and modeling methods, examination and diagnosis of actual cement and concrete structures, and the exploration of potential improvements in materials.