Maria P. Davydova, Ting Xu, Alexander M. Agafontsev, Lingqiang Meng, Mariusz Wolff, Maxim Yu. Petyuk, Irina Yu. Bagryanskaya, Alexey S. Berezin, Alexey V. Tkachev, Hong Meng, Alexander V. Artem'ev
{"title":"Toward Rhenium‐based Circularly Polarized OLEDs Using Tailored Chiral Re(CO)3 Emitters","authors":"Maria P. Davydova, Ting Xu, Alexander M. Agafontsev, Lingqiang Meng, Mariusz Wolff, Maxim Yu. Petyuk, Irina Yu. Bagryanskaya, Alexey S. Berezin, Alexey V. Tkachev, Hong Meng, Alexander V. Artem'ev","doi":"10.1002/anie.202419788","DOIUrl":null,"url":null,"abstract":"Chiral rhenium(I) emitters showing circularly polarized phosphorescence (CPP) are an attractive mainstay for CP organic light‐emitting diodes (CP‐OLEDs). However, the efficiency of such emitters is not ideal, and they have never been explored for circularly polarized electroluminescence (CPEL) applications. Here, we have tailored robust chiral Re(I) complexes with improved CPP properties, and firstly demonstrated CPEL from rhenium emitters. The designed chiral Re(I) complexes exhibit a yellow CPP with enhanced |glum| factors (up to 2.5×10–2) and a good quantum efficiency. The pioneering Re(I)‐based CP‐OLEDs (based on the obtained emitters) exhibit yellow CPEL with |gEL| factors of up to 6.2×10–3 and maximal external quantum efficiency of 13.2%. Furthermore, we have demonstrated for the first time a suppressive effect of a magnetic field on the CPP strength of Re(I) emitters. This work highlights the good potential of chiral Re(I) emitters for CPEL applications, and opens up a new shortcut to CPP‐active Re(I) complexes.","PeriodicalId":125,"journal":{"name":"Angewandte Chemie International Edition","volume":"22 1","pages":""},"PeriodicalIF":16.1000,"publicationDate":"2024-12-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Angewandte Chemie International Edition","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1002/anie.202419788","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Toward Rhenium‐based Circularly Polarized OLEDs Using Tailored Chiral Re(CO)3 Emitters
Chiral rhenium(I) emitters showing circularly polarized phosphorescence (CPP) are an attractive mainstay for CP organic light‐emitting diodes (CP‐OLEDs). However, the efficiency of such emitters is not ideal, and they have never been explored for circularly polarized electroluminescence (CPEL) applications. Here, we have tailored robust chiral Re(I) complexes with improved CPP properties, and firstly demonstrated CPEL from rhenium emitters. The designed chiral Re(I) complexes exhibit a yellow CPP with enhanced |glum| factors (up to 2.5×10–2) and a good quantum efficiency. The pioneering Re(I)‐based CP‐OLEDs (based on the obtained emitters) exhibit yellow CPEL with |gEL| factors of up to 6.2×10–3 and maximal external quantum efficiency of 13.2%. Furthermore, we have demonstrated for the first time a suppressive effect of a magnetic field on the CPP strength of Re(I) emitters. This work highlights the good potential of chiral Re(I) emitters for CPEL applications, and opens up a new shortcut to CPP‐active Re(I) complexes.
期刊介绍:
Angewandte Chemie, a journal of the German Chemical Society (GDCh), maintains a leading position among scholarly journals in general chemistry with an impressive Impact Factor of 16.6 (2022 Journal Citation Reports, Clarivate, 2023). Published weekly in a reader-friendly format, it features new articles almost every day. Established in 1887, Angewandte Chemie is a prominent chemistry journal, offering a dynamic blend of Review-type articles, Highlights, Communications, and Research Articles on a weekly basis, making it unique in the field.