IF 8.1 1区 工程技术 Q1 ENGINEERING, CHEMICAL
Zicheng Du, Baojie Liu, Xiaoying Liu, Lu Liu, Chen Liang, Shuangquan Yao, Chengrong Qin
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引用次数: 0

摘要

从木质纤维素生物质中分离出低凝木质素对实现其全成分转化具有重要意义。本研究提出了一种新型高效、环保的醇/酸预处理系统,该系统以 1,4- 丁二醇(1,4-BDO)为溶剂,结合对甲苯磺酸(p-TsOH),可有效分离低凝聚木质素。结果表明,该系统能在短时间内去除 85.55% 的半纤维素和 84.78% 的木质素,纤维素的保留率很高。基于 1,4-BDO 分子保护木质素结构的现象,回收的低缩合木质素结构含有主要的脂肪羟基结构,剩余的固体表面木质素缩合粒较少,纤维结晶度高,有利于制备高价值产品。此外,木质素溶解动力学研究表明,p-TsOH/1,4-BDO 预处理的反应活化能较低,阐明了 1,4-BDO 对木质素高效溶解的溶解作用。最后,结合密度泛函理论(DFT)从分子水平阐明了 1,4-BDO 与木质素结构之间的氢键和共轭效应可有效降低木质素分子的自缩合反应。该研究实现了木质纤维素生物质的有效分离,为 1,4-BDO 在生物质组分分离中的应用提供了理论依据,推动了绿色高效组分分离技术的发展。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Study on high efficiency separation of low condensation lignin and its dissolution mechanism by 1, 4 butanediol combined with p-toluene sulfonic acid pretreatment system

Study on high efficiency separation of low condensation lignin and its dissolution mechanism by 1, 4 butanediol combined with p-toluene sulfonic acid pretreatment system
Separating low condensed lignin from lignocellulosic biomass is of great importance for achieving its full component conversion. This study proposed a new efficient and environmentally friendly alcohol/acid pretreatment system using 1,4-butanediol (1,4-BDO) as a solvent, combined with p-toluene sulfonic acid (p-TsOH) to efficiently separate low condensed lignin. The results showed that the system could remove 85.55 % of hemicellulose and 84.78 % of lignin in a short time, with a high retention rate of cellulose. Based on the phenomenon of 1,4-BDO molecule protecting lignin structure, the recovered low-condensed lignin structure contains the main aliphatic hydroxyl structure, and the remaining solid surface lignin condensation grains were fewer, and the fiber crystallinity was high, which was beneficial for the preparation of high-value products. In addition, the lignin dissolution kinetics revealed that the p-TsOH/1,4-BDO pretreatment had a lower reaction activation energy, clarifying the solvation effect of 1,4-BDO on efficient lignin dissolution. Finally, combining density functional theory (DFT) from the molecular level clarified that the hydrogen bonding and conjugated effect between 1,4-BDO and lignin structure could effectively reduce the self-condensation reaction of lignin molecules. This study achieved effective separation of lignocellulosic biomass, providing a theoretical basis for the application of 1,4-BDO in biomass component separation, and promoting the development of green and efficient component separation technologies.
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来源期刊
Separation and Purification Technology
Separation and Purification Technology 工程技术-工程:化工
CiteScore
14.00
自引率
12.80%
发文量
2347
审稿时长
43 days
期刊介绍: Separation and Purification Technology is a premier journal committed to sharing innovative methods for separation and purification in chemical and environmental engineering, encompassing both homogeneous solutions and heterogeneous mixtures. Our scope includes the separation and/or purification of liquids, vapors, and gases, as well as carbon capture and separation techniques. However, it's important to note that methods solely intended for analytical purposes are not within the scope of the journal. Additionally, disciplines such as soil science, polymer science, and metallurgy fall outside the purview of Separation and Purification Technology. Join us in advancing the field of separation and purification methods for sustainable solutions in chemical and environmental engineering.
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