{"title":"碳纳米管催化和静电纳米颗粒过滤改善氢氧化铵-柴油混合物的环保性能","authors":"Suresh Vellaiyan","doi":"10.1016/j.jhazmat.2024.136906","DOIUrl":null,"url":null,"abstract":"This study explores the integration of ammonium hydroxide with diesel fuel, focusing on enhancing combustion efficiency and reducing emissions. The research addresses the challenge of ammonia's high activation energy during decomposition by introducing a carbon nanotube catalyst, which significantly improves catalytic performance. Additionally, an electrostatic precipitator (ESP) was developed to capture nanoparticles from engine exhaust, preventing their release into the atmosphere. The synthesized nanoparticles were characterized using SEM, EDX, XRD, and FTIR, providing insights into their structural and surface properties. Various blends of ammonium hydroxide (5% and 10%) with diesel fuel, enriched with 100 ppm of nanocatalyst, were tested in a diesel engine under different conditions. The results showed notable improvements in engine efficiency and fuel consumption, reducing by 8.2% and 7.9%, respectively. Emissions of hydrocarbons, carbon monoxide, and nitrogen oxides decreased by 19.7%, 10.7%, and 5.6%, respectively, demonstrating the potential of the nanocatalyst-enhanced ammonium hydroxide fuel blend. Furthermore, a comparative characterization of nanoparticles synthesized and those collected from the ESP plates confirms the ESP’s effectiveness in capturing degraded nanoparticles. This emphasizes the critical role of advanced filtration technologies in mitigating environmental pollution from engine exhaust. The study’s findings contribute to the ongoing efforts to develop cleaner, more efficient fuel technologies.","PeriodicalId":361,"journal":{"name":"Journal of Hazardous Materials","volume":"17 1","pages":""},"PeriodicalIF":11.3000,"publicationDate":"2024-12-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Environmental Performance Improvement of Ammonium Hydroxide-Diesel Blends via Carbon Nanotube Catalysis and Electrostatic Nanoparticle Filtration\",\"authors\":\"Suresh Vellaiyan\",\"doi\":\"10.1016/j.jhazmat.2024.136906\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"This study explores the integration of ammonium hydroxide with diesel fuel, focusing on enhancing combustion efficiency and reducing emissions. The research addresses the challenge of ammonia's high activation energy during decomposition by introducing a carbon nanotube catalyst, which significantly improves catalytic performance. Additionally, an electrostatic precipitator (ESP) was developed to capture nanoparticles from engine exhaust, preventing their release into the atmosphere. The synthesized nanoparticles were characterized using SEM, EDX, XRD, and FTIR, providing insights into their structural and surface properties. Various blends of ammonium hydroxide (5% and 10%) with diesel fuel, enriched with 100 ppm of nanocatalyst, were tested in a diesel engine under different conditions. The results showed notable improvements in engine efficiency and fuel consumption, reducing by 8.2% and 7.9%, respectively. Emissions of hydrocarbons, carbon monoxide, and nitrogen oxides decreased by 19.7%, 10.7%, and 5.6%, respectively, demonstrating the potential of the nanocatalyst-enhanced ammonium hydroxide fuel blend. Furthermore, a comparative characterization of nanoparticles synthesized and those collected from the ESP plates confirms the ESP’s effectiveness in capturing degraded nanoparticles. This emphasizes the critical role of advanced filtration technologies in mitigating environmental pollution from engine exhaust. The study’s findings contribute to the ongoing efforts to develop cleaner, more efficient fuel technologies.\",\"PeriodicalId\":361,\"journal\":{\"name\":\"Journal of Hazardous Materials\",\"volume\":\"17 1\",\"pages\":\"\"},\"PeriodicalIF\":11.3000,\"publicationDate\":\"2024-12-15\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Hazardous Materials\",\"FirstCategoryId\":\"93\",\"ListUrlMain\":\"https://doi.org/10.1016/j.jhazmat.2024.136906\",\"RegionNum\":1,\"RegionCategory\":\"环境科学与生态学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"ENGINEERING, ENVIRONMENTAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Hazardous Materials","FirstCategoryId":"93","ListUrlMain":"https://doi.org/10.1016/j.jhazmat.2024.136906","RegionNum":1,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"ENGINEERING, ENVIRONMENTAL","Score":null,"Total":0}
Environmental Performance Improvement of Ammonium Hydroxide-Diesel Blends via Carbon Nanotube Catalysis and Electrostatic Nanoparticle Filtration
This study explores the integration of ammonium hydroxide with diesel fuel, focusing on enhancing combustion efficiency and reducing emissions. The research addresses the challenge of ammonia's high activation energy during decomposition by introducing a carbon nanotube catalyst, which significantly improves catalytic performance. Additionally, an electrostatic precipitator (ESP) was developed to capture nanoparticles from engine exhaust, preventing their release into the atmosphere. The synthesized nanoparticles were characterized using SEM, EDX, XRD, and FTIR, providing insights into their structural and surface properties. Various blends of ammonium hydroxide (5% and 10%) with diesel fuel, enriched with 100 ppm of nanocatalyst, were tested in a diesel engine under different conditions. The results showed notable improvements in engine efficiency and fuel consumption, reducing by 8.2% and 7.9%, respectively. Emissions of hydrocarbons, carbon monoxide, and nitrogen oxides decreased by 19.7%, 10.7%, and 5.6%, respectively, demonstrating the potential of the nanocatalyst-enhanced ammonium hydroxide fuel blend. Furthermore, a comparative characterization of nanoparticles synthesized and those collected from the ESP plates confirms the ESP’s effectiveness in capturing degraded nanoparticles. This emphasizes the critical role of advanced filtration technologies in mitigating environmental pollution from engine exhaust. The study’s findings contribute to the ongoing efforts to develop cleaner, more efficient fuel technologies.
期刊介绍:
The Journal of Hazardous Materials serves as a global platform for promoting cutting-edge research in the field of Environmental Science and Engineering. Our publication features a wide range of articles, including full-length research papers, review articles, and perspectives, with the aim of enhancing our understanding of the dangers and risks associated with various materials concerning public health and the environment. It is important to note that the term "environmental contaminants" refers specifically to substances that pose hazardous effects through contamination, while excluding those that do not have such impacts on the environment or human health. Moreover, we emphasize the distinction between wastes and hazardous materials in order to provide further clarity on the scope of the journal. We have a keen interest in exploring specific compounds and microbial agents that have adverse effects on the environment.