水热法合成的 Zn2SiO4:Eu3+ 红色荧光粉的发光应用

IF 2.8 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY
S. Sebastian, P. Diana, S. Saravanakumar, V. Sivakumar, T. K. Thirumaliasamy, V. Ganesh, H. Algarni
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引用次数: 0

摘要

本研究介绍了通过水热法合成的 Zn2SiO4:Eu3+ (Zn2-xEuxSiO4;x = 0、0.015、0.03、0.045 和 0.06)荧光粉的发光特性。研究利用各种分析和光谱技术,重点研究了在 Zn2SiO4 主基中掺杂铕(Eu)对其结构和发光特性的影响。掺杂 0 至 6 wt % Eu 的 Zn2SiO4 的带隙值从 5.01 eV 降至 3.20 eV。光致发光(PL)光谱显示存在红色发射,峰值强度在 614 nm 处,这证实了 Eu 成功地掺入了 Zn2SiO4 晶格,这是由于诱导电偶极子转变引起的转变(5D0 → 7F2)。利用三指数拟合技术测定了平均发光衰减寿命,发现其值为 33 ns,这为潜在的光电应用提供了宝贵的启示。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Zn2SiO4:Eu3+ Red phosphor synthesized by hydrothermal method for light emitting applications

This study presents the luminescence characterization of Zn2SiO4:Eu3+ (Zn2-xEuxSiO4; x = 0, 0.015, 0.03, 0.045, and 0.06) phosphors, synthesized through the hydrothermal approach. The investigation focused on the influence of europium (Eu) doping in the Zn2SiO4 host on the structural and luminescence properties, utilizing various analytical and spectroscopic techniques. The band gap values are decreased from 5.01 to 3.20 eV for the 0 to 6 wt % Eu doped Zn2SiO4. The photoluminescence (PL) spectra revealed the presence of a red emission with the peak intensity observed at 614 nm, confirming the successful incorporation of Eu into the Zn2SiO4 lattice due to the transition (5D0 → 7F2), attributed to an induced electric dipole transition. The average luminescence decay lifetime was determined using the tri-exponential fitting technique, and the value was found to be 33 ns, which showcased valuable insights for potential optoelectronic applications.

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来源期刊
Applied Physics A
Applied Physics A 工程技术-材料科学:综合
CiteScore
4.80
自引率
7.40%
发文量
964
审稿时长
38 days
期刊介绍: Applied Physics A publishes experimental and theoretical investigations in applied physics as regular articles, rapid communications, and invited papers. The distinguished 30-member Board of Editors reflects the interdisciplinary approach of the journal and ensures the highest quality of peer review.
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