通过共轭聚合物多组分工程将卤化物包晶直接集成到离子门控晶体管中

IF 6.3 2区 材料科学 Q2 CHEMISTRY, PHYSICAL
Benjamin Nketia-Yawson, Vivian Nketia-Yawson, Hyungju Ahn, Jea Woong Jo
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引用次数: 0

摘要

离子栅电介质具有大电容和高诱导载流子密度调制的特点,因此被广泛应用于不同类别半导体的电子器件中。然而,尽管金属卤化物包晶体半导体可对诱导载流子密度进行多功能控制,但其有限的化学稳定性限制了其在溶液处理离子栅晶体管(IGT)中的应用。在这项工作中,我们展示了如何将溶剂、溶液处理离子聚合物电介质和包光体-共轭聚合物半导体混合物用于高性能、低电压的正交工程 IGT。通过为溶液处理离子聚合物电介质选择合适的正交溶剂,在混合工程包晶石-聚合物半导体层顶部实现了稳健的界面特性,且无损坏。使用优化的甲脒三碘化铅(FAPbI3)-聚(3-己基噻吩-2,5-二基)(P3HT)混合物制造的 IGT 在≤- 1.5 V 的工作电压下具有 >9 cm2 V-1 s-1 的高室温空穴迁移率、>103 的导通/截止比、高再现性以及在环境条件下出色的工作稳定性。这种新型混合包晶 IGT 具有独特的离子栅电介质,可以作为开发基于包晶的柔性可变形晶体管、生理传感设备和相关电子器件的试验平台。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Direct integration of halide perovskite into ionic-gated transistors by multicomponent engineering with conjugated polymer

Direct integration of halide perovskite into ionic-gated transistors by multicomponent engineering with conjugated polymer
The large capacitance and high induced-carrier density modulation of ionic gate dielectrics have resulted in their substantial integration into diverse electronic device applications with different classes of semiconductors. However, despite the versatile control of induced carrier density in metal halide perovskite semiconductors, limited chemical stability has restricted their consideration for solution-processed ionic-gated transistors (IGTs). In this work, we demonstrate the engineering of solvents, solution-processed ionic polymer dielectric, and perovskite-conjugated polymer semiconductor blends for high-performance and low-voltage orthogonally engineered IGTs. By selecting a suitable orthogonal solvent for the solution-processed ionic polymer dielectric, robust interfacial characteristics were achieved atop the blend-engineered perovskite–polymer semiconductor layer without damage. The fabricated IGTs with an optimized formamidinium lead triiodide (FAPbI3)-poly(3-hexylthiophene-2,5-diyl) (P3HT) blend showed a high room-temperature hole mobility of >9 cm2 V−1 s−1 under ≤− 1.5 V operation with an on/off ratio of >103, high reproducibility, and excellent operational stability under ambient conditions. This novel hybrid perovskite IGTs with unique ionic gate dielectric could be a testbed for developing flexible and deformable perovskite-based transistors, physiological sensing devices, and related electronics.
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来源期刊
Applied Surface Science
Applied Surface Science 工程技术-材料科学:膜
CiteScore
12.50
自引率
7.50%
发文量
3393
审稿时长
67 days
期刊介绍: Applied Surface Science covers topics contributing to a better understanding of surfaces, interfaces, nanostructures and their applications. The journal is concerned with scientific research on the atomic and molecular level of material properties determined with specific surface analytical techniques and/or computational methods, as well as the processing of such structures.
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