铁光催化中的转化配体效应

IF 19.1 1区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY

Chem Pub Date : 2024-12-12 DOI:10.1016/j.chempr.2024.11.008

Luisa Zach, Jola Pospech

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引用次数: 0

摘要

铁光催化一直受到各种底物范围可调配体缺乏的限制。Ackerman-Biegasiewicz等人最近在《化学催化》中证明了二乙基三胺（DETA）在铁催化的吉斯型添加物中是一种转化配体。该平台使底物与游离胺、醇和硼酯有效耦合，突出了铁在光氧化还原催化中作为贵金属可持续替代品的潜力。

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Transformative ligand effects in iron photocatalysis

Iron photocatalysis has been constrained by a lack of tunable ligands for diverse substrate scopes. Ackerman-Biegasiewicz et al. demonstrate diethylenetriamine (DETA) as a transformative ligand in Fe-catalyzed Giese-type additions recently in Chem Catalysis. This platform enables effective coupling of substrates with free amines, alcohols, and boronic esters, highlighting iron’s potential as a sustainable alternative to precious metals in photoredox catalysis.

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来源期刊

Chem Environmental Science-Environmental Chemistry

CiteScore

32.40

自引率

1.30%

发文量

281

期刊介绍： Chem, affiliated with Cell as its sister journal, serves as a platform for groundbreaking research and illustrates how fundamental inquiries in chemistry and its related fields can contribute to addressing future global challenges. It was established in 2016, and is currently edited by Robert Eagling.