Nanoconfined catalytic macrostructures for advanced water remediation: From basic understanding to future application strategies

In recent years, nanoconfined catalytic macrostructures applied to advanced oxidation processes (AOPs) have been rapidly developed, effectively solving the problems of traditional heterogeneous AOPs, such as mass transfer limitation, limited diffusion of short-lived reactive oxygen species (ROS), and aggregation/leaching of catalysts. Compared with the traditional heterogeneous AOPs systems, the nanoconfined catalytic macrostructures have unique interactions between the oxidants, catalysts, ROS and micropollutants, which could significantly increase the yield and mass transfer of ROS. At present, there is a lack of comprehensive reviews on the nanoconfined catalytic macrostructures from basic theory to application performances and future development strategies. This study reviewed the preparation routines of various nanoconfined catalytic macrostructures, assessed their structural differences, catalytic properties and nanoconfined catalytic mechanisms via integrated density functional theory (DFT) and molecular dynamics (MD) stimulations. We also proposed the future strategies for nanoconfined catalytic macrostructures in combination with the machine learning, which could provide key information on the feasibility of the technology and future research directions. This review aims to enhance scholarly interest in the application of nanoconfined macrostructures in the AOPs fields, anticipating significant technical feasibilities for scale-up AOPs application of nanoconfinement.