{"title":"缺乏NO3 -阴离子条件下铀酰硝酸溶液的制备","authors":"V. L. Sofronov, V. A. Lavrentyev","doi":"10.1134/S1066362224050035","DOIUrl":null,"url":null,"abstract":"<p>The dissolution of uranium oxides of various chemical compositions at different nitric acid solution concentrations and flow rates with obtaining uranyl nitrate solutions with a deficiency of NO<sub>3</sub><sup>–</sup> anions was studied. The dependences of the solubility of uranyl hydroxonitrates on the nitric acid deficiency relative to stoichiometry and temperature were determined. It was shown that the solubility of hydroxonitrates in these solutions is higher than the solubility of uranyl nitrates obtained with stoichiometric or excess nitric acid content. In addition, the solubility of hydroxonitrates increases with temperature. The kinetics of uranium oxide dissolution in various temperature regimes with the formation of solutions with nitric acid deficiency relative to stoichiometry were studied. The initial dissolution rate of U<sub>3</sub>O<sub>8</sub> in uranyl nitrate solution was determined in the temperature range from 40 to 104°C.</p>","PeriodicalId":747,"journal":{"name":"Radiochemistry","volume":"66 5","pages":"614 - 623"},"PeriodicalIF":0.9000,"publicationDate":"2024-12-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Obtaining Nitric Acid Solutions of Uranyl at Deficiency of NO3– Anions\",\"authors\":\"V. L. Sofronov, V. A. Lavrentyev\",\"doi\":\"10.1134/S1066362224050035\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>The dissolution of uranium oxides of various chemical compositions at different nitric acid solution concentrations and flow rates with obtaining uranyl nitrate solutions with a deficiency of NO<sub>3</sub><sup>–</sup> anions was studied. The dependences of the solubility of uranyl hydroxonitrates on the nitric acid deficiency relative to stoichiometry and temperature were determined. It was shown that the solubility of hydroxonitrates in these solutions is higher than the solubility of uranyl nitrates obtained with stoichiometric or excess nitric acid content. In addition, the solubility of hydroxonitrates increases with temperature. The kinetics of uranium oxide dissolution in various temperature regimes with the formation of solutions with nitric acid deficiency relative to stoichiometry were studied. The initial dissolution rate of U<sub>3</sub>O<sub>8</sub> in uranyl nitrate solution was determined in the temperature range from 40 to 104°C.</p>\",\"PeriodicalId\":747,\"journal\":{\"name\":\"Radiochemistry\",\"volume\":\"66 5\",\"pages\":\"614 - 623\"},\"PeriodicalIF\":0.9000,\"publicationDate\":\"2024-12-11\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Radiochemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S1066362224050035\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Radiochemistry","FirstCategoryId":"1085","ListUrlMain":"https://link.springer.com/article/10.1134/S1066362224050035","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
Obtaining Nitric Acid Solutions of Uranyl at Deficiency of NO3– Anions
The dissolution of uranium oxides of various chemical compositions at different nitric acid solution concentrations and flow rates with obtaining uranyl nitrate solutions with a deficiency of NO3– anions was studied. The dependences of the solubility of uranyl hydroxonitrates on the nitric acid deficiency relative to stoichiometry and temperature were determined. It was shown that the solubility of hydroxonitrates in these solutions is higher than the solubility of uranyl nitrates obtained with stoichiometric or excess nitric acid content. In addition, the solubility of hydroxonitrates increases with temperature. The kinetics of uranium oxide dissolution in various temperature regimes with the formation of solutions with nitric acid deficiency relative to stoichiometry were studied. The initial dissolution rate of U3O8 in uranyl nitrate solution was determined in the temperature range from 40 to 104°C.
期刊介绍：
Radiochemistry is a journal that covers the theoretical and applied aspects of radiochemistry, including basic nuclear physical properties of radionuclides; chemistry of radioactive elements and their compounds; the occurrence and behavior of natural and artificial radionuclides in the environment; nuclear fuel cycle; radiochemical analysis methods and devices; production and isolation of radionuclides, synthesis of labeled compounds, new applications of radioactive tracers; radiochemical aspects of nuclear medicine; radiation chemistry and after-effects of nuclear transformations.
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