离子置换诱导的卡戈梅晶格和呼吸卡戈梅晶格的转变

IF 4.7 2区化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR

Inorganic Chemistry Pub Date : 2024-12-09 DOI:10.1021/acs.inorgchem.4c04734

Zhangzhen He, Mengsi Zhang, Zhiying Zhao, Meiyan Cui

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引用次数: 0

摘要

通过将PbOCu3(SeO3)2(NO3)F的F -离子取代(OH)−基团合成PbOCu3(SeO3)2(NO3)(OH)，显示出kagom晶格和呼吸kagom晶格的转变。这种替换没有改变它们的层内铁磁相互作用和层间反铁磁相互作用，但对n温度和临界场有轻微影响，其中PbOCu3(SeO3)2(NO3)（OH）在TN = 29.3 K时具有AFM有序，当施加1.45 T的临界磁场时，在2 K时可以发生场致变磁跃迁。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Transformation of Kagomé and Breathing Kagomé Lattices Induced by Ion Replacement

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Transformation of Kagomé and Breathing Kagomé Lattices Induced by Ion Replacement

PbOCu₃(SeO₃)₂(NO₃)(OH) was synthesized by means of a replacement of (OH)⁻ groups for F^– ions of PbOCu₃(SeO₃)₂(NO₃)F, showing a transformation of kagomé and breathing kagomé lattices. Such a replacement did not change their intralayer ferromagnetic interactions and interlayer antiferromagnetic (AFM) interactions but slightly affected the Néel temperature and critical field, where PbOCu₃(SeO₃)₂(NO₃)(OH) possesses an AFM ordering at T_N = 29.3 K, and a field-induced metamagnetic transition can occur at 2 K while a critical magnetic field of 1.45 T is applied.

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来源期刊

Inorganic Chemistry 化学-无机化学与核化学

CiteScore

7.60

自引率

13.00%

发文量

1960

审稿时长

1.9 months

期刊介绍： Inorganic Chemistry publishes fundamental studies in all phases of inorganic chemistry. Coverage includes experimental and theoretical reports on quantitative studies of structure and thermodynamics, kinetics, mechanisms of inorganic reactions, bioinorganic chemistry, and relevant aspects of organometallic chemistry, solid-state phenomena, and chemical bonding theory. Emphasis is placed on the synthesis, structure, thermodynamics, reactivity, spectroscopy, and bonding properties of significant new and known compounds.