含1-甲基吡啶和3-溴-1-甲基吡啶阳离子的1D聚合物碘锑酸盐（III）：结构和性质

IF 1.1 3区化学 Q4 CHEMISTRY, INORGANIC & NUCLEAR

Russian Journal of Coordination Chemistry Pub Date : 2024-12-08 DOI:10.1134/S1070328424600700

I. A. Shentseva, A. N. Usol’tsev, N. A. Korobeinikov, S. A. Adonin

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引用次数: 0

摘要

在乙腈和丙酮的混合物中，SbI3与吡啶族阳离子的碘化物反应得到两个聚合碘锑酸盐配合物：（1-MePy）{[SbI4]} (I)和（3-Br-1-MePy）{[SbI4]} （II）。用热重法评价了化合物I和II的热稳定性。从漫反射光谱中估计了光学禁带隙。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

1D Polymeric Iodoantimonates(III) with 1-Methylpyridinium and 3-Bromo-1-methylpyridinium Cations: Structures and Properties

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1D Polymeric Iodoantimonates(III) with 1-Methylpyridinium and 3-Bromo-1-methylpyridinium Cations: Structures and Properties

The reactions of SbI₃ with iodides of cations of the pyridinium family in a mixture of acetonitrile and acetone afford two polymeric iodoantimonate complexes: (1-MePy){[SbI₄]} (I) and (3-Br-1-MePy){[SbI₄]} (II). Specific features of the crystal structures are determined by X-ray diffraction (XRD). The thermal stability of compounds I and II is evaluated by thermogravimetry. The optical forbidden bandgaps are estimated from the diffuse reflectance spectra.

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来源期刊

Russian Journal of Coordination Chemistry 化学-无机化学与核化学

CiteScore

2.40

自引率

15.80%

发文量

审稿时长

7.2 months

期刊介绍： Russian Journal of Coordination Chemistry is a journal that publishes reviews, original papers, and short communications on all aspects of theoretical and experimental coordination chemistry. Modern coordination chemistry is an interdisciplinary science that makes a bridge between inorganic, organic, physical, analytical, and biological chemistry.