开发具有抗s形CD-ee依赖性的手性聚集体：使用中位异构体调节由对映体诱导的动态聚集体

IF 4.3 2区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

Chemical Communications Pub Date : 2024-12-20 DOI:10.1039/d4cc05345a

Xiao-Yan Lin , Jin-Ling Shi , Qian Wang , Yue-Bo Yu , Xuan-Xuan Chen , Xiaosheng Yan , Xin Wu , Jian-Bin Lin , Zhao Li , Yun-Bao Jiang

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引用次数: 0

摘要

我们报道了使用酒石酸的中位异构体，中位酒石酸，在L-/ d -酒石酸对映体存在的情况下，调整含硼酸基团的苝酰二亚胺染料的动态聚集体的手性。CD-ee的依赖关系由S型变为反S型。发现了中位酒石酸引起的手性聚集体结构的变化。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Developing chiral aggregates exhibiting anti-S-shaped CD-ee dependence: using a meso-isomer to tune dynamic aggregates induced by enantiomers†

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Developing chiral aggregates exhibiting anti-S-shaped CD-ee dependence: using a meso-isomer to tune dynamic aggregates induced by enantiomers†

We report the use of the meso-isomer of tartaric acid, meso-tartaric acid, to tune the chirality of the dynamic aggregates of a perylenebisimide dye bearing boronic acid groups in the presence of enantiomeric l-/d-tartaric acid. The CD-ee dependence changes from S- to anti-S-shaped. A change in the structures of the chiral aggregates led by the meso-tartaric acid is identified.

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来源期刊

Chemical Communications 化学-化学综合

CiteScore

8.60

自引率

4.10%

发文量

2705

审稿时长

1.4 months

期刊介绍： ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.