三元补偿实现近红外可视化的高灵敏度高效上转换装置

IF 26.8 1区 材料科学 Q1 CHEMISTRY, MULTIDISCIPLINARY
Shilong Dong, Jin Li, Tianjiao Ma, Ming Zhang, Lei Zhu, Xiaxin Gao, Manping Ma, Wenqiang Yuan, Zaiyu Wang, Feng Liu, Xuesong Jiang
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引用次数: 0

摘要

除了用于红外可视化的晶体光电二极管,由于不透明度和复杂的光刻工艺的限制,有机上转换器件(UCD)已经成为一种潜在的替代方案。在本研究中,在非富勒烯有源层中实现三元补偿策略,以减小探测器的暗电流,提高探测器的检测性能,实现近红外光(NIR)可视化的高灵敏度高效上转换器件。该器件在0.4 mW cm−2的功率密度下解析980 nm红外信号时,实现了16.68%的红外到可见光上转换效率。此外,通过取代半透明基质电极,进一步制备了大面积(12.25 cm2)、重量轻(6.5 g含封装)、无像素(等效分辨率1270 ppi)、响应时间为微秒的半透明(AVT≈40%)UCD。所制备的UCD在无像素主动红外裸眼可视化和红外反监视中得到了验证,促进了红外可视化技术的进步。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Ternary Compensation Enables High-sensitive Efficient Upconversion Device for NIR Visualization

Ternary Compensation Enables High-sensitive Efficient Upconversion Device for NIR Visualization

Ternary Compensation Enables High-sensitive Efficient Upconversion Device for NIR Visualization

Ternary Compensation Enables High-sensitive Efficient Upconversion Device for NIR Visualization

Ternary Compensation Enables High-sensitive Efficient Upconversion Device for NIR Visualization

Ternary Compensation Enables High-sensitive Efficient Upconversion Device for NIR Visualization

Beyond the crystalline photodiodes for infrared visualization, with the limitation of opacity and complex lithographic processes, organic upconversion device (UCD) have emerged as a potential alternative. In this research, a ternary compensation strategy is implemented in a non-fullerene-based active layer to reduce the dark current of the detector and enhance its detection performance, which enables high-sensitive efficient upconversion device for near-infrared light (NIR) visualization. The device achieves an infrared-to-visible upconversion efficiency of 16.68% when resolving the 980 nm infrared signal at a power density of 0.4 mW cm−2. In addition, by replacing the semitransparent matrix electrodes, a large-area (12.25 cm2) is further fabricated, lightweight (6.5 g containing encapsulation), pixel-less (equivalent resolution 1270 ppi), and semitransparent (AVT ≈40%) UCD with microsecond response time. The fabricated UCD is demonstrated in pixel-less active infrared naked-eye visualization and infrared counter-surveillance, fostering the advancement of infrared visualization technology.

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来源期刊
Advanced Materials
Advanced Materials 工程技术-材料科学:综合
CiteScore
43.00
自引率
4.10%
发文量
2182
审稿时长
2 months
期刊介绍: Advanced Materials, one of the world's most prestigious journals and the foundation of the Advanced portfolio, is the home of choice for best-in-class materials science for more than 30 years. Following this fast-growing and interdisciplinary field, we are considering and publishing the most important discoveries on any and all materials from materials scientists, chemists, physicists, engineers as well as health and life scientists and bringing you the latest results and trends in modern materials-related research every week.
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