Shilong Dong, Jin Li, Tianjiao Ma, Ming Zhang, Lei Zhu, Xiaxin Gao, Manping Ma, Wenqiang Yuan, Zaiyu Wang, Feng Liu, Xuesong Jiang
{"title":"三元补偿实现近红外可视化的高灵敏度高效上转换装置","authors":"Shilong Dong, Jin Li, Tianjiao Ma, Ming Zhang, Lei Zhu, Xiaxin Gao, Manping Ma, Wenqiang Yuan, Zaiyu Wang, Feng Liu, Xuesong Jiang","doi":"10.1002/adma.202412678","DOIUrl":null,"url":null,"abstract":"<p>Beyond the crystalline photodiodes for infrared visualization, with the limitation of opacity and complex lithographic processes, organic upconversion device (UCD) have emerged as a potential alternative. In this research, a ternary compensation strategy is implemented in a non-fullerene-based active layer to reduce the dark current of the detector and enhance its detection performance, which enables high-sensitive efficient upconversion device for near-infrared light (NIR) visualization. The device achieves an infrared-to-visible upconversion efficiency of 16.68% when resolving the 980 nm infrared signal at a power density of 0.4 mW cm<sup>−2</sup>. In addition, by replacing the semitransparent matrix electrodes, a large-area (12.25 cm<sup>2</sup>) is further fabricated, lightweight (6.5 g containing encapsulation), pixel-less (equivalent resolution 1270 ppi), and semitransparent (AVT ≈40%) UCD with microsecond response time. The fabricated UCD is demonstrated in pixel-less active infrared naked-eye visualization and infrared counter-surveillance, fostering the advancement of infrared visualization technology.</p>","PeriodicalId":114,"journal":{"name":"Advanced Materials","volume":"37 4","pages":""},"PeriodicalIF":26.8000,"publicationDate":"2024-12-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Ternary Compensation Enables High-sensitive Efficient Upconversion Device for NIR Visualization\",\"authors\":\"Shilong Dong, Jin Li, Tianjiao Ma, Ming Zhang, Lei Zhu, Xiaxin Gao, Manping Ma, Wenqiang Yuan, Zaiyu Wang, Feng Liu, Xuesong Jiang\",\"doi\":\"10.1002/adma.202412678\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>Beyond the crystalline photodiodes for infrared visualization, with the limitation of opacity and complex lithographic processes, organic upconversion device (UCD) have emerged as a potential alternative. In this research, a ternary compensation strategy is implemented in a non-fullerene-based active layer to reduce the dark current of the detector and enhance its detection performance, which enables high-sensitive efficient upconversion device for near-infrared light (NIR) visualization. The device achieves an infrared-to-visible upconversion efficiency of 16.68% when resolving the 980 nm infrared signal at a power density of 0.4 mW cm<sup>−2</sup>. In addition, by replacing the semitransparent matrix electrodes, a large-area (12.25 cm<sup>2</sup>) is further fabricated, lightweight (6.5 g containing encapsulation), pixel-less (equivalent resolution 1270 ppi), and semitransparent (AVT ≈40%) UCD with microsecond response time. The fabricated UCD is demonstrated in pixel-less active infrared naked-eye visualization and infrared counter-surveillance, fostering the advancement of infrared visualization technology.</p>\",\"PeriodicalId\":114,\"journal\":{\"name\":\"Advanced Materials\",\"volume\":\"37 4\",\"pages\":\"\"},\"PeriodicalIF\":26.8000,\"publicationDate\":\"2024-12-06\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Advanced Materials\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://advanced.onlinelibrary.wiley.com/doi/10.1002/adma.202412678\",\"RegionNum\":1,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Advanced Materials","FirstCategoryId":"88","ListUrlMain":"https://advanced.onlinelibrary.wiley.com/doi/10.1002/adma.202412678","RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Ternary Compensation Enables High-sensitive Efficient Upconversion Device for NIR Visualization
Beyond the crystalline photodiodes for infrared visualization, with the limitation of opacity and complex lithographic processes, organic upconversion device (UCD) have emerged as a potential alternative. In this research, a ternary compensation strategy is implemented in a non-fullerene-based active layer to reduce the dark current of the detector and enhance its detection performance, which enables high-sensitive efficient upconversion device for near-infrared light (NIR) visualization. The device achieves an infrared-to-visible upconversion efficiency of 16.68% when resolving the 980 nm infrared signal at a power density of 0.4 mW cm−2. In addition, by replacing the semitransparent matrix electrodes, a large-area (12.25 cm2) is further fabricated, lightweight (6.5 g containing encapsulation), pixel-less (equivalent resolution 1270 ppi), and semitransparent (AVT ≈40%) UCD with microsecond response time. The fabricated UCD is demonstrated in pixel-less active infrared naked-eye visualization and infrared counter-surveillance, fostering the advancement of infrared visualization technology.
期刊介绍:
Advanced Materials, one of the world's most prestigious journals and the foundation of the Advanced portfolio, is the home of choice for best-in-class materials science for more than 30 years. Following this fast-growing and interdisciplinary field, we are considering and publishing the most important discoveries on any and all materials from materials scientists, chemists, physicists, engineers as well as health and life scientists and bringing you the latest results and trends in modern materials-related research every week.