新型二茂铁和钌茂烯基镍螯合物

IF 1.7 4区化学 Q3 CHEMISTRY, MULTIDISCIPLINARY

Russian Chemical Bulletin Pub Date : 2024-12-06 DOI:10.1007/s11172-024-4399-z

S. V. Safronov, S. A. Kuklin, N. V. Abramova, Yu. V. Nelyubina

引用次数: 0

摘要

首先合成了二茂铁镍螯合物NiCl[{2,5-(But2PCH2)2C5H2}Fe(C5H5)] （3a）和NiCl[{2,5-(But2PCH2)2C5H2}Ru(C5H5)] (3b)，并用1H、31P{1H}和13C{1H} NMR对其进行了表征。通过单晶x射线衍射确定了配合物3b的结构。

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New ferrocene- and ruthenocene-based nickel pincer complexes

First ferrocene- and ruthenocene-based nickel pincer complexes, NiCl[{2,5-(Bu^t₂PCH₂)₂C₅H₂}Fe(C₅H₅)] (3a) and NiCl[{2,5-(Bu^t₂PCH₂)₂C₅H₂}Ru(C₅H₅)] (3b), respectively, were synthesized and characterized by ¹H, ³¹P{¹H}, and ¹³C{¹H} NMR spectroscopy. The structure of complex 3b was established by single-crystal X-ray diffraction.

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来源期刊

Russian Chemical Bulletin 化学-化学综合

CiteScore

2.70

自引率

47.10%

发文量

257

审稿时长

3-8 weeks

期刊介绍： Publishing nearly 500 original articles a year, by leading Scientists from Russia and throughout the world, Russian Chemical Bulletin is a prominent international journal. The coverage of the journal spans practically all areas of fundamental chemical research and is presented in five sections: General and Inorganic Chemistry; Physical Chemistry; Organic Chemistry; Organometallic Chemistry; Chemistry of Natural Compounds and Bioorganic Chemistry.