含荧光基团的非对称氧化三芳膦的合成

IF 1.7 4区化学 Q3 CHEMISTRY, MULTIDISCIPLINARY

Russian Chemical Bulletin Pub Date : 2024-12-06 DOI:10.1007/s11172-024-4418-0

O. V. Bykhovskaya, I. Yu. Kudryavtsev, T. V. Baulina, M. P. Pasechnik, V. K. Brel

引用次数: 0

摘要

三（2-羟基苯基）氧化膦与N-（3-羟丙基）-4-硝基-1,8-萘酰亚胺的Mitsunobu反应仅产生两个酚基的烷基化反应。通过与丁胺的反应，合成产物的芳香族硝基被BuNH取代。合成产物具有荧光团性质。

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Synthesis of non-symmetrical triarylphosphine oxide with fluorophore groups

The Mitsunobu reaction of tris(2-hydroxyphenyl)phosphine oxide with N-(3-hydroxypropyl)-4-nitro-1,8-naphthalimide resulted in alkylation of only two phenolic groups. The aromatic nitro groups of the synthesized product were replaced by the BuNH groups by the reaction with butylamine. The synthesized product exhibited fluorophore properties.

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来源期刊

Russian Chemical Bulletin 化学-化学综合

CiteScore

2.70

自引率

47.10%

发文量

257

审稿时长

3-8 weeks

期刊介绍： Publishing nearly 500 original articles a year, by leading Scientists from Russia and throughout the world, Russian Chemical Bulletin is a prominent international journal. The coverage of the journal spans practically all areas of fundamental chemical research and is presented in five sections: General and Inorganic Chemistry; Physical Chemistry; Organic Chemistry; Organometallic Chemistry; Chemistry of Natural Compounds and Bioorganic Chemistry.