联苯菊酯的环境命运:对其土壤吸附和降解研究的洞察。

IF 2.3 3区 化学 Q3 CHEMISTRY, ANALYTICAL
Journal of Analytical Methods in Chemistry Pub Date : 2024-11-25 eCollection Date: 2024-01-01 DOI:10.1155/jamc/8868954
Jehad S Al-Hawadi, Sara Majid, Khuram Shahzad Ahmad, Gaber E Eldesoky, Ghulam Abbas Ashraf
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引用次数: 0

摘要

为了充分了解每种农药的行为及其与土壤和环境的相互作用,对每种农药进行彻底而细致的分析是必要的。在本研究中,随机选择10个具有不同特征的非均质土壤样品,进行了生物降解、水解和光解的吸附试验和崩解试验。对于吸附试验,采用了批平衡法,揭示了对土壤物理化学特性的依赖。联苯菊酯的分配系数(kd)为7.27 ~ 25.89 μg·ml-1, r2为0.92 ~ 0.99。土壤的各种理化特征与不同的吸附结果相关联,表明土壤是基于负热力学值的放热吸附反应。水解、土壤诱导生物降解和光解过程的半衰期最短,分别为13.5天、12天和121.5天。根据这些发现,联苯菊酯在土壤中具有适度的结合力和稳定性,这使得母体和子分子的部分分解具有挑战性。这项研究提高了我们对联苯菊酯恶化过程的认识,并有助于利用自然过程创建生态恢复的前沿战略。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Bifenthrin's Environmental Fate: An Insight Into Its Soil Sorption and Degradation Studies.

To fully comprehend each pesticide's behavior and interactions with soil and the environment, a thorough and nuanced analysis of each one is thought necessary. In this study, 10 randomly selected heterogeneous soil samples, each with distinct characteristics, were subjected to sorption trials as well as disintegration tests using biodegradation, hydrolysis, and photolysis. For sorption tests, the batch equilibrium approach was used, which revealed a dependence on the soils' physicochemical characteristics. Bifenthrin's distribution coefficient (K d ) varied from 7.27 to 25.89 μg·ml-1, with R 2 values varying from 0.92 to 0.99. Each soil physicochemical characteristic was associated with the various sorptive outcomes, which suggested an exothermic adsorptive reaction based on the negative thermodynamic values. The hydrolysis, soil-induced biodegradation, and photolysis processes had the shortest half-lives of bifenthrin, measuring 13.5 days, 12 days, and 121.5 days, respectively. According to these findings, bifenthrin has a moderate amount of binding and stability in soil, which makes partial decomposition of parent and daughter molecules challenging. This research advances our knowledge of bifenthrin's deteriorating processes and aids in the creation of cutting-edge strategies for ecological restoration using natural processes.

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来源期刊
Journal of Analytical Methods in Chemistry
Journal of Analytical Methods in Chemistry CHEMISTRY, ANALYTICAL-ENGINEERING, CIVIL
CiteScore
4.80
自引率
3.80%
发文量
79
审稿时长
6-12 weeks
期刊介绍: Journal of Analytical Methods in Chemistry publishes papers reporting methods and instrumentation for chemical analysis, and their application to real-world problems. Articles may be either practical or theoretical. Subject areas include (but are by no means limited to): Separation Spectroscopy Mass spectrometry Chromatography Analytical Sample Preparation Electrochemical analysis Hyphenated techniques Data processing As well as original research, Journal of Analytical Methods in Chemistry also publishes focused review articles that examine the state of the art, identify emerging trends, and suggest future directions for developing fields.
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