Min Xu , Shengbo Zhang , Jiafang Liu , Yaqian Xin , Yong Jiang , Yunxia Zhang , Guozhong Wang , Haimin Zhang
{"title":"氧化亚铜纳米线上α-酮酸高选择性电催化还原胺化制丙氨酸。","authors":"Min Xu , Shengbo Zhang , Jiafang Liu , Yaqian Xin , Yong Jiang , Yunxia Zhang , Guozhong Wang , Haimin Zhang","doi":"10.1039/d4cc05399k","DOIUrl":null,"url":null,"abstract":"<div><div>Herein, cuprous oxide (Cu<sub>2</sub>O) nanowires are synthesized by a simple process, realizing the high selectivity electrocatalytic reductive amination of biomass-derived pyruvate to alanine (organic product selectivity: ∼100%). Importantly, a total of 8 different amino acids can be efficiently synthesized using Cu<sub>2</sub>O nanowires, confirming the universality of Cu<sub>2</sub>O nanowires.</div></div>","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":"61 2","pages":"Pages 306-309"},"PeriodicalIF":4.2000,"publicationDate":"2024-11-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"High selectivity electrocatalytic reductive amination of α-keto acids to alanine over cuprous oxide nanowires†\",\"authors\":\"Min Xu , Shengbo Zhang , Jiafang Liu , Yaqian Xin , Yong Jiang , Yunxia Zhang , Guozhong Wang , Haimin Zhang\",\"doi\":\"10.1039/d4cc05399k\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Herein, cuprous oxide (Cu<sub>2</sub>O) nanowires are synthesized by a simple process, realizing the high selectivity electrocatalytic reductive amination of biomass-derived pyruvate to alanine (organic product selectivity: ∼100%). Importantly, a total of 8 different amino acids can be efficiently synthesized using Cu<sub>2</sub>O nanowires, confirming the universality of Cu<sub>2</sub>O nanowires.</div></div>\",\"PeriodicalId\":67,\"journal\":{\"name\":\"Chemical Communications\",\"volume\":\"61 2\",\"pages\":\"Pages 306-309\"},\"PeriodicalIF\":4.2000,\"publicationDate\":\"2024-11-25\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chemical Communications\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/org/science/article/pii/S1359734524025527\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemical Communications","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S1359734524025527","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
High selectivity electrocatalytic reductive amination of α-keto acids to alanine over cuprous oxide nanowires†
Herein, cuprous oxide (Cu2O) nanowires are synthesized by a simple process, realizing the high selectivity electrocatalytic reductive amination of biomass-derived pyruvate to alanine (organic product selectivity: ∼100%). Importantly, a total of 8 different amino acids can be efficiently synthesized using Cu2O nanowires, confirming the universality of Cu2O nanowires.
期刊介绍:
ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.