卡唑型液态有机氢载体中负载亚微米LaNi5的一锅合成

IF 4.2 2区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

Chemical Communications Pub Date : 2024-12-03 DOI:10.1039/d4cc05419a

Hongen Yu , Yuxuan Shi , Zewei Xie , Rumei Jin , Youyu Lin , Dongsheng Geng , Xingguo Li , Jie Zheng

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引用次数: 0

摘要

金属氢化物在含氢反应中是很有前途的催化剂。然而，由于金属氢化物对氧和水的敏感性，缩小尺寸和装载是困难的。本文提出了一种简单的一锅熔盐合成方法来合成多孔La(OH)3负载LaNi5。所合成的催化剂在催化有机液体氢载体n -乙基咔唑的可逆储氢方面表现出明显的改善。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

One-pot synthesis of supported sub-micron LaNi5 for hydrogen storage in a carbazole-type liquid organic hydrogen carrier†

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One-pot synthesis of supported sub-micron LaNi5 for hydrogen storage in a carbazole-type liquid organic hydrogen carrier†

Metal hydrides are promising catalysts in hydrogen-involving reactions. However, downsizing and loading metal hydrides is difficult due to their sensitivity towards oxygen and water. Here, a simple one-pot molten salt synthetical method is proposed to synthesize porous La(OH)₃-supported LaNi₅. The as-synthesized catalyst shows an evident improvement in catalyzing reversible hydrogen storage in liquid organic hydrogen carrier N-ethylcarbazole.

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来源期刊

Chemical Communications 化学-化学综合

CiteScore

8.60

自引率

4.10%

发文量

2705

审稿时长

1.4 months

期刊介绍： ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.