咔唑-磷腈基聚合物高效萃取电子废弃物中的金及贵重元素

IF 4.3 3区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY
Evren Cucu, Betul Ari Engin, Murat Tunc, Ramazan Altundas and Ali Enis Sadak*, 
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引用次数: 0

摘要

工业和技术的不断进步大大增加了电子垃圾,这导致了有价金属储量的枯竭。因此,有效和可持续地回收电子垃圾中的贵金属是至关重要的。本研究介绍了一种新的方法,将咔唑-磷腈基聚合物EBE-06应用于两阶段浸出法中,以有效地提取金属。在第一浸出阶段,锡在控制ph的酸溶液中被选择性分离。在第二阶段,有价金属如金通过吸附在EBE-06上被回收。该聚合物在1 h内对金的吸附率为99%,与pH无关,每克聚合物的最大吸附量为1.787 g金。解吸过程的效率为95%,聚合物在三个循环使用中保持94%的效率。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Carbazole–Phosphazene Based Polymer for Efficient Extraction of Gold and Precious Elements from Electronic Waste

The continuous advancement of industry and technology has significantly increased electronic waste, which contributes to the depletion of valuable metal reserves. Therefore, it is crucial to recycle precious metals in electronic waste effectively and sustainably. This study introduces a novel approach by applying a carbazole–phosphazene-based polymer, EBE-06, in a two-stage leaching method for efficient metal extraction. In the first leaching stage, tin is selectively separated using an acid solution at a controlled pH. In the second stage, valuable metals such as gold are recovered through adsorption onto EBE-06. The polymer exhibited a 99% gold adsorption rate within 1 h, independent of pH, and a maximum adsorption capacity of 1.787 g of gold per gram of polymer. The desorption process yielded 95% efficiency, with the polymer maintaining 94% efficiency over three cycles of use.

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来源期刊
ACS Omega
ACS Omega Chemical Engineering-General Chemical Engineering
CiteScore
6.60
自引率
4.90%
发文量
3945
审稿时长
2.4 months
期刊介绍: ACS Omega is an open-access global publication for scientific articles that describe new findings in chemistry and interfacing areas of science, without any perceived evaluation of immediate impact.
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