自由基机制硼酸化方法的最新进展

IF 5.5 1区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

Chinese Journal of Chemistry Pub Date : 2024-10-17 DOI:10.1002/cjoc.202400694

Chang Lian, Jianning Zhang, Di Qiu, Fanyang Mo

{"title":"自由基机制硼酸化方法的最新进展","authors":"Chang Lian, Jianning Zhang, Di Qiu, Fanyang Mo","doi":"10.1002/cjoc.202400694","DOIUrl":null,"url":null,"abstract":"<div>\n \n \n <section>\n \n <p>We reviewed works on radical borylation reactions since 2020 from two aspects. <b>1. Borylation from alkyl or aryl radicals</b>: This approach involves the generation of alkyl or aryl radicals from various precursors such as halides and carboxylic acids, followed by their reaction with diboron reagents to form boron esters. <b>2. Borylation from boron-centered radicals</b>: This approach involves generating boron-centered radicals, which then react with substrates to achieve borylation.</p>\n \n <p>\n </p>\n </section>\n \n <section>\n \n <h3> Key Scientists</h3>\n \n <p></p>\n </section>\n </div>","PeriodicalId":151,"journal":{"name":"Chinese Journal of Chemistry","volume":"43 1","pages":"104-115"},"PeriodicalIF":5.5000,"publicationDate":"2024-10-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Recent Advances in Methodologies for Radical-Mechanistic Borylation†\",\"authors\":\"Chang Lian, Jianning Zhang, Di Qiu, Fanyang Mo\",\"doi\":\"10.1002/cjoc.202400694\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div>\\n \\n \\n <section>\\n \\n <p>We reviewed works on radical borylation reactions since 2020 from two aspects. <b>1. Borylation from alkyl or aryl radicals</b>: This approach involves the generation of alkyl or aryl radicals from various precursors such as halides and carboxylic acids, followed by their reaction with diboron reagents to form boron esters. <b>2. Borylation from boron-centered radicals</b>: This approach involves generating boron-centered radicals, which then react with substrates to achieve borylation.</p>\\n \\n <p>\\n </p>\\n </section>\\n \\n <section>\\n \\n <h3> Key Scientists</h3>\\n \\n <p></p>\\n </section>\\n </div>\",\"PeriodicalId\":151,\"journal\":{\"name\":\"Chinese Journal of Chemistry\",\"volume\":\"43 1\",\"pages\":\"104-115\"},\"PeriodicalIF\":5.5000,\"publicationDate\":\"2024-10-17\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chinese Journal of Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/cjoc.202400694\",\"RegionNum\":1,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chinese Journal of Chemistry","FirstCategoryId":"92","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/cjoc.202400694","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}

引用次数: 0

摘要

本文从两个方面综述了2020年以来有关自由基硼化反应的研究进展。1. 烷基或芳基自由基的硼化：这种方法涉及从各种前体（如卤化物和羧酸）生成烷基或芳基自由基，然后与二硼试剂反应生成硼酯。2. 以硼为中心的自由基的硼化：这种方法包括产生以硼为中心的自由基，然后与底物反应以实现硼化。关键的科学家

本文章由计算机程序翻译，如有差异，请以英文原文为准。

查看原文本刊更多论文

Recent Advances in Methodologies for Radical-Mechanistic Borylation†

We reviewed works on radical borylation reactions since 2020 from two aspects. 1. Borylation from alkyl or aryl radicals: This approach involves the generation of alkyl or aryl radicals from various precursors such as halides and carboxylic acids, followed by their reaction with diboron reagents to form boron esters. 2. Borylation from boron-centered radicals: This approach involves generating boron-centered radicals, which then react with substrates to achieve borylation.

Key Scientists

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Chinese Journal of Chemistry 化学-化学综合

CiteScore

8.80

自引率

14.80%

发文量

422

审稿时长

1.7 months

期刊介绍： The Chinese Journal of Chemistry is an international forum for peer-reviewed original research results in all fields of chemistry. Founded in 1983 under the name Acta Chimica Sinica English Edition and renamed in 1990 as Chinese Journal of Chemistry, the journal publishes a stimulating mixture of Accounts, Full Papers, Notes and Communications in English.