开发低成本析氧反应催化剂的电子结构调制策略评估

Electron Pub Date : 2024-10-24 DOI:10.1002/elt2.65
Zhen Zhang, Shaobo Han, Cheng Li, Chao Cai, Meng Danny Gu
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引用次数: 0

摘要

析氧反应(OER)是电化学合成反应的关键,包括制氢和有机氢化反应。然而,现有OER催化剂(主要是Ir/Ru及其衍生的氧化物)的高成本限制了它们在电化学合成中的实际应用。为了开发一种低成本、高效率的替代品,我们需要更深入地了解驱动OER的机制以及催化剂的电子结构和活性位点之间的关系。本文综述了近年来催化剂的研究进展,重点介绍了电子结构调制策略及其后续活性的提高。最重要的是,我们指出了进一步工作的研究方向。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Assessing electronic structure modulation strategies toward the development of low-cost oxygen evolution reaction catalysts

Assessing electronic structure modulation strategies toward the development of low-cost oxygen evolution reaction catalysts

Oxygen evolution reactions (OER) are critical to electrochemical synthesis reactions, including hydrogen production and organic hydrogenation. However, the high cost of existing OER catalysts (primarily Ir/Ru and its derived oxides) limits their practical application for electrochemical synthesis. To develop a low-cost, high-efficiency alternative, we need a deeper understanding of both the mechanisms that drive OER and the relationship between the catalyst's electronic structure and active sites. Here, we summarized recent developments of catalysts, especially focusing on the electronic structure modulation strategies and their subsequent activity enhancement. Most importantly, we pointed out the study directions for further work.

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