一系列三维同聚物Ln(III) 2-碘对苯二甲酸酯：结构特征和发光行为

IF 3.8 3区材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY

Optical Materials Pub Date : 2024-11-22 DOI:10.1016/j.optmat.2024.116468

Alexander S. Zaguzin , Mikhail A. Bondarenko , Pavel A. Abramov , Marianna I. Rakhmanova , Dmitry A. Zherebtsov , Vladimir P. Fedin , Sergey A. Adonin

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引用次数: 0

摘要

得到了以Ln3+和2-二对苯二甲酸酯（2-I-bdc）为基料的9种三维金属有机骨架，分子式为{[Ln2(2-I-bdc)3(H2O)]·xH2O·yCH3CN} （Ln = La, Pr, Nd, Sm, Eu, Gd, Tb， Dy和Ho， 1-9）。根据x射线衍射，这些配合物分别属于两种结构类型（La to Nd和Sm to Ho）。1-9系列中的一些配合物具有发光性质。

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A series of three-dimensional homoligand Ln(III) 2-iodoterephthalates: Structural features and luminescent behavior

A series of nine 3D metal-organic frameworks based on Ln³⁺ and 2-diodoterephthalate (2-I-bdc) with general formula {[Ln₂(2-I-bdc)₃(H₂O)]·xH₂O·yCH₃CN} (Ln = La, Pr, Nd, Sm, Eu, Gd, Tb, Dy and Ho, 1–9) were obtained. According to X-ray diffractometry, all these complexes belong to two structural types (La to Nd and Sm to Ho, respectively). Some of complexes in the 1–9 series demonstrate luminescent properties.

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来源期刊

Optical Materials 工程技术-材料科学：综合

CiteScore

6.60

自引率

12.80%

发文量

1265

审稿时长

38 days

期刊介绍： Optical Materials has an open access mirror journal Optical Materials: X, sharing the same aims and scope, editorial team, submission system and rigorous peer review. The purpose of Optical Materials is to provide a means of communication and technology transfer between researchers who are interested in materials for potential device applications. The journal publishes original papers and review articles on the design, synthesis, characterisation and applications of optical materials. OPTICAL MATERIALS focuses on: • Optical Properties of Material Systems; • The Materials Aspects of Optical Phenomena; • The Materials Aspects of Devices and Applications. Authors can submit separate research elements describing their data to Data in Brief and methods to Methods X.