Mechanistic insights into the use of flotation tail coal for enhanced water electrolysis in hydrogen production

Coal-assisted water electrolysis for hydrogen production (CAWE) is a promising method for the efficient utilization of coal resources and the sustainable generation of hydrogen. However, identifying a cost-effective and efficient carbon source remains a critical and ongoing challenge. This study proposes the use of flotation tail coal as a novel and efficient carbon source for water electrolysis. Through a combination of electrochemical experiments, thermodynamic analysis, and comprehensive material characterization techniques, this research explores the effectiveness of tail coal-assisted water electrolysis for hydrogen production (TCAWE) in enhancing hydrogen production efficiency. It is found that the catalytic effect of minerals, particularly iron and manganese ions, is instrumental in significantly reducing energy consumption and enhancing the anodic oxidation reactions in the CAWE process. Flotation tail coal, with its high content of these catalytic minerals and favorable hydrophilic surface properties, not only lowers the electrolysis voltage but also increases the hydrogen yield compared to traditional coal sources. This research innovatively demonstrates that utilizing flotation tail coal in water electrolysis offers a dual benefit: it provides a cost-effective, abundant carbon source while promoting a more efficient and sustainable hydrogen production process. Additionally, this approach is expected to facilitate the resource utilization of waste flotation tail coal.