光催化n-芳基丙烯酰胺分子内碳氮化成3-（叠氮多甲基）吲哚-2-酮

IF 1.8 4区化学 Q3 CHEMISTRY, MULTIDISCIPLINARY

Mendeleev Communications Pub Date : 2024-11-01 DOI:10.1016/j.mencom.2024.10.021

Jue Wang , Mei Hong , Chengxian Liu , Liang Wang

引用次数: 0

摘要

在可见光的辅助下，2,4,5,6-四（咔唑-9-基）-1,3-二苯基苯在室温下与1-叠氮-1 - λ -3 -苯并[d][1,2]碘醇和-3(1H)- 1 （N3-Togni试剂）产生3-（叠氮甲基）吲哚-2- 1进行了n-芳基丙烯酰胺的分子内碳氮化反应。后者提供了由N3-Togni试剂形成的叠氮自由基。所研究的衬底范围涉及12个实例。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Photocatalytic intramolecular carboazidation of N-arylacrylamides into 3-(azidomethyl)indolin-2-ones

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Photocatalytic intramolecular carboazidation of N-arylacrylamides into 3-(azidomethyl)indolin-2-ones

Intramolecular carboazidation of N-arylacrylamides with 1-azido-1λ³-benzo[d][1,2]iodaoxol-3(1H)-one (the N₃-Togni reagent) affording 3-(azidomethyl)indolin-2-ones proceeds at room temperature under visible light irradiation with 2,4,5,6-tetra(carbazol-9-yl)-1,3-dicyanobenzene assistance. The latter provides the formation of azido radicals from the N₃-Togni reagent. The investigated substrate scope involves 12 examples.

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来源期刊

Mendeleev Communications 化学-化学综合

CiteScore

3.00

自引率

21.10%

发文量

226

审稿时长

4-8 weeks

期刊介绍： Mendeleev Communications is the journal of the Russian Academy of Sciences, launched jointly by the Academy of Sciences of the USSR and the Royal Society of Chemistry (United Kingdom) in 1991. Starting from 1st January 2007, Elsevier is the new publishing partner of Mendeleev Communications. Mendeleev Communications publishes short communications in chemistry. The journal primarily features papers from the Russian Federation and the other states of the former USSR. However, it also includes papers by authors from other parts of the world. Mendeleev Communications is not a translated journal, but instead is published directly in English. The International Editorial Board is composed of eminent scientists who provide advice on refereeing policy.