二乙烯基吩噻嗪侧面的四苯并咪唑：作为氮杂迈克尔受体的 AIEgens 对生物胺蒸汽的浓度调节反应

IF 4.2 2区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

Chemical Communications Pub Date : 2024-12-03 DOI:10.1039/d4cc05725b

Sameer Singh , Kalyaneswar Mandal , Manab Chakravarty

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引用次数: 0

摘要

在二乙烯基吩噻嗪定子两侧的四苯并咪唑转子可作为红色 AIEgens 实现，并且新近被确定为识别生物胺蒸汽的高效氮-迈克尔受体。通过快速的偶氮-迈克尔加成和同时发生的反向-Knoevenagel 反应，弱红色发射固体显示出蓝移发射。浓度变化可提高结晶度，促进辐射衰变，从而提供独特的发射。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Tetra-benzimidazoles flanking divinyl-phenothiazine: AIEgens as aza-Michael acceptors in concentration-tuned responses to biogenic amine vapors†

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Tetra-benzimidazoles flanking divinyl-phenothiazine: AIEgens as aza-Michael acceptors in concentration-tuned responses to biogenic amine vapors†

Tetra-benzimidazole rotors flanking a divinyl-phenothiazine stator are realized as red AIEgens and newly identified as efficient aza-Michael acceptors for the identification of biogenic amine vapors. Weakly red-emissive solids display a blue-shifted turn-on emission by rapid aza-Michael addition and simultaneous reverse Knoevenagel reactions. Concentration variation imposes better crystallinity and facilitates radiative decay, offering distinct emissions.

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来源期刊

Chemical Communications 化学-化学综合

CiteScore

8.60

自引率

4.10%

发文量

2705

审稿时长

1.4 months

期刊介绍： ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.