Arti Khajuria, Vishav Deep Sharma, Pooja Khajuria, Ram Prakash
{"title":"K2MgP2O7 纳米磷中活化的 Eu3+ 离子的合成、下转换发光和 Judd-Ofelt 分析","authors":"Arti Khajuria, Vishav Deep Sharma, Pooja Khajuria, Ram Prakash","doi":"10.1016/j.physb.2024.416750","DOIUrl":null,"url":null,"abstract":"<div><div>Over the preceding several decades, numerous red phosphors have been synthesized and developed. The currently using light emitting diode (LED) phosphor spectrum lacks red light, leading to inadequate production of white LED material and a low color rendering index, which impacts lighting effects. The present work outlines the synthesis, photoluminescence, Judd-Ofelt analysis, and optical properties of the promising red phosphor K<sub>2</sub>MgP<sub>2</sub>O<sub>7</sub>: Eu<sup>3+</sup>. When the synthesized sample is exposed to ultraviolet light (392 nm), it emits the characteristic emission of Eu<sup>3+</sup> ions. The most prominent emission peak is centered at wavelength 617 nm which gives emission in the crimson region of the color gamut. The value of the branching ratio is above 50 % for the most intense transition dictates the possible laser emission transition. The findings of all these studies demonstrate that K<sub>2</sub>MgP<sub>2</sub>O<sub>7</sub>: Eu<sup>3+</sup> is a potential red phosphor for use in white LEDs.</div></div>","PeriodicalId":20116,"journal":{"name":"Physica B-condensed Matter","volume":"698 ","pages":"Article 416750"},"PeriodicalIF":2.8000,"publicationDate":"2024-11-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis, down-conversion luminescence, and Judd-Ofelt analysis of Eu3+ ions activated in K2MgP2O7 nanophosphor\",\"authors\":\"Arti Khajuria, Vishav Deep Sharma, Pooja Khajuria, Ram Prakash\",\"doi\":\"10.1016/j.physb.2024.416750\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Over the preceding several decades, numerous red phosphors have been synthesized and developed. The currently using light emitting diode (LED) phosphor spectrum lacks red light, leading to inadequate production of white LED material and a low color rendering index, which impacts lighting effects. The present work outlines the synthesis, photoluminescence, Judd-Ofelt analysis, and optical properties of the promising red phosphor K<sub>2</sub>MgP<sub>2</sub>O<sub>7</sub>: Eu<sup>3+</sup>. When the synthesized sample is exposed to ultraviolet light (392 nm), it emits the characteristic emission of Eu<sup>3+</sup> ions. The most prominent emission peak is centered at wavelength 617 nm which gives emission in the crimson region of the color gamut. The value of the branching ratio is above 50 % for the most intense transition dictates the possible laser emission transition. The findings of all these studies demonstrate that K<sub>2</sub>MgP<sub>2</sub>O<sub>7</sub>: Eu<sup>3+</sup> is a potential red phosphor for use in white LEDs.</div></div>\",\"PeriodicalId\":20116,\"journal\":{\"name\":\"Physica B-condensed Matter\",\"volume\":\"698 \",\"pages\":\"Article 416750\"},\"PeriodicalIF\":2.8000,\"publicationDate\":\"2024-11-16\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Physica B-condensed Matter\",\"FirstCategoryId\":\"101\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0921452624010913\",\"RegionNum\":3,\"RegionCategory\":\"物理与天体物理\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"PHYSICS, CONDENSED MATTER\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Physica B-condensed Matter","FirstCategoryId":"101","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0921452624010913","RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"PHYSICS, CONDENSED MATTER","Score":null,"Total":0}
引用次数: 0
摘要
在过去的几十年里,人们合成并开发了大量红色荧光粉。目前使用的发光二极管(LED)荧光粉光谱缺乏红光,导致白光 LED 材料产量不足,显色指数低,影响照明效果。本研究概述了前景看好的红色荧光粉 K2MgP2O7: Eu3+ 的合成、光致发光、Judd-Ofelt 分析和光学特性。当合成样品暴露在紫外线(392 纳米)下时,会发出 Eu3+ 离子的特征发射。最突出的发射峰位于波长 617 纳米处,在色域的深红色区域发射。最强烈转变的支化比值高于 50%,这就决定了可能的激光发射转变。所有这些研究结果表明,K2MgP2O7: Eu3+ 是一种可用于白光 LED 的红色荧光粉。
Synthesis, down-conversion luminescence, and Judd-Ofelt analysis of Eu3+ ions activated in K2MgP2O7 nanophosphor
Over the preceding several decades, numerous red phosphors have been synthesized and developed. The currently using light emitting diode (LED) phosphor spectrum lacks red light, leading to inadequate production of white LED material and a low color rendering index, which impacts lighting effects. The present work outlines the synthesis, photoluminescence, Judd-Ofelt analysis, and optical properties of the promising red phosphor K2MgP2O7: Eu3+. When the synthesized sample is exposed to ultraviolet light (392 nm), it emits the characteristic emission of Eu3+ ions. The most prominent emission peak is centered at wavelength 617 nm which gives emission in the crimson region of the color gamut. The value of the branching ratio is above 50 % for the most intense transition dictates the possible laser emission transition. The findings of all these studies demonstrate that K2MgP2O7: Eu3+ is a potential red phosphor for use in white LEDs.
期刊介绍:
Physica B: Condensed Matter comprises all condensed matter and material physics that involve theoretical, computational and experimental work.
Papers should contain further developments and a proper discussion on the physics of experimental or theoretical results in one of the following areas:
-Magnetism
-Materials physics
-Nanostructures and nanomaterials
-Optics and optical materials
-Quantum materials
-Semiconductors
-Strongly correlated systems
-Superconductivity
-Surfaces and interfaces