{"title":"通过聚多巴胺涂层增强无粘结剂三元硒化铜锰纳米复合电极的电化学储能,用于准固态混合超级电容器","authors":"Mandar Vasant Paranjape, Edugulla Girija Shankar, Manchi Punnarao, Jae Su Yu","doi":"10.1016/j.est.2024.114801","DOIUrl":null,"url":null,"abstract":"<div><div>Owing to promising reliability, high energy storage capability, good stability, etc., nanostructured bimetallic selenides have attracted widespread interest in establishing supercapacitor devices with auspicious electrochemical properties. Focusing on this, herein, we proposed a novel polydopamine (PDA)-coated nanostructured copper manganese selenide (CuMn<sub>2</sub>Se<sub>4</sub>) on nickel foam via a hydrothermal method. The chemical composition of the cathode electrode was modified according to the chemical formula of Cu<sub>x</sub>Mn<sub>2-x</sub>Se<sub>4</sub> (x = 0, 0.5, and 1) (CMS), and its effect on electrochemical properties as well as on surface morphology was investigated. The optimized CMS electrode exhibited an evenly spread petal-like lawn structure, offering rapid electron/ion kinetics, which results in improved capacitive properties. Furthermore, PDA as a redox-active neurotransmitter was evenly coated on the optimized CMS (i.e., PDA@CMS) to increase electron availability, thus enhancing energy storage capacity. The PDA@CMS electrode showed a superior specific capacitance of 3140 F g<sup>−1</sup> at 3 A g<sup>−1</sup> of current density. The quasi-solid-state hybrid supercapacitor was fabricated using PDA@CMS as a positive electrode and radish-derived carbon as a negative electrode with gel-type electrolyte, which delivered the power and energy densities of 7750 W kg<sup>−1</sup> and 21.85 Wh kg<sup>−1</sup>, respectively with superior cycling stability (96.5 % capacitance retention over 10,000 cycles).</div></div>","PeriodicalId":15942,"journal":{"name":"Journal of energy storage","volume":"105 ","pages":""},"PeriodicalIF":8.9000,"publicationDate":"2024-11-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Enhanced electrochemical energy storage of binder-free ternary copper manganese selenide nanocomposite electrodes via polydopamine coating for quasi-solid-state hybrid supercapacitors\",\"authors\":\"Mandar Vasant Paranjape, Edugulla Girija Shankar, Manchi Punnarao, Jae Su Yu\",\"doi\":\"10.1016/j.est.2024.114801\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Owing to promising reliability, high energy storage capability, good stability, etc., nanostructured bimetallic selenides have attracted widespread interest in establishing supercapacitor devices with auspicious electrochemical properties. Focusing on this, herein, we proposed a novel polydopamine (PDA)-coated nanostructured copper manganese selenide (CuMn<sub>2</sub>Se<sub>4</sub>) on nickel foam via a hydrothermal method. The chemical composition of the cathode electrode was modified according to the chemical formula of Cu<sub>x</sub>Mn<sub>2-x</sub>Se<sub>4</sub> (x = 0, 0.5, and 1) (CMS), and its effect on electrochemical properties as well as on surface morphology was investigated. The optimized CMS electrode exhibited an evenly spread petal-like lawn structure, offering rapid electron/ion kinetics, which results in improved capacitive properties. Furthermore, PDA as a redox-active neurotransmitter was evenly coated on the optimized CMS (i.e., PDA@CMS) to increase electron availability, thus enhancing energy storage capacity. The PDA@CMS electrode showed a superior specific capacitance of 3140 F g<sup>−1</sup> at 3 A g<sup>−1</sup> of current density. The quasi-solid-state hybrid supercapacitor was fabricated using PDA@CMS as a positive electrode and radish-derived carbon as a negative electrode with gel-type electrolyte, which delivered the power and energy densities of 7750 W kg<sup>−1</sup> and 21.85 Wh kg<sup>−1</sup>, respectively with superior cycling stability (96.5 % capacitance retention over 10,000 cycles).</div></div>\",\"PeriodicalId\":15942,\"journal\":{\"name\":\"Journal of energy storage\",\"volume\":\"105 \",\"pages\":\"\"},\"PeriodicalIF\":8.9000,\"publicationDate\":\"2024-11-28\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of energy storage\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2352152X24043871\",\"RegionNum\":2,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"ENERGY & FUELS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of energy storage","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2352152X24043871","RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"ENERGY & FUELS","Score":null,"Total":0}
引用次数: 0
摘要
由于具有可靠性高、储能能力强、稳定性好等优点,纳米双金属硒化物在建立具有良好电化学特性的超级电容器器件方面引起了广泛的兴趣。为此,我们通过水热法在泡沫镍上提出了一种新型聚多巴胺(PDA)包覆的纳米结构硒化铜锰(CuMn2Se4)。根据 CuxMn2-xSe4(x = 0、0.5 和 1)(CMS)的化学式对阴极电极的化学成分进行了改良,并研究了其对电化学性能和表面形貌的影响。优化后的 CMS 电极呈现出均匀分布的花瓣状草坪结构,提供了快速的电子/离子动力学,从而改善了电容特性。此外,作为一种具有氧化还原活性的神经递质,PDA 被均匀涂覆在优化的 CMS(即 PDA@CMS)上,以增加电子的可用性,从而提高储能能力。在 3 A g-1 的电流密度下,PDA@CMS 电极的比电容高达 3140 F g-1。以 PDA@CMS 为正极、萝卜提取物碳为负极、凝胶型电解质制成的准固态混合超级电容器的功率密度和能量密度分别为 7750 W kg-1 和 21.85 Wh kg-1,并具有优异的循环稳定性(10000 次循环后电容保持率为 96.5%)。
Enhanced electrochemical energy storage of binder-free ternary copper manganese selenide nanocomposite electrodes via polydopamine coating for quasi-solid-state hybrid supercapacitors
Owing to promising reliability, high energy storage capability, good stability, etc., nanostructured bimetallic selenides have attracted widespread interest in establishing supercapacitor devices with auspicious electrochemical properties. Focusing on this, herein, we proposed a novel polydopamine (PDA)-coated nanostructured copper manganese selenide (CuMn2Se4) on nickel foam via a hydrothermal method. The chemical composition of the cathode electrode was modified according to the chemical formula of CuxMn2-xSe4 (x = 0, 0.5, and 1) (CMS), and its effect on electrochemical properties as well as on surface morphology was investigated. The optimized CMS electrode exhibited an evenly spread petal-like lawn structure, offering rapid electron/ion kinetics, which results in improved capacitive properties. Furthermore, PDA as a redox-active neurotransmitter was evenly coated on the optimized CMS (i.e., PDA@CMS) to increase electron availability, thus enhancing energy storage capacity. The PDA@CMS electrode showed a superior specific capacitance of 3140 F g−1 at 3 A g−1 of current density. The quasi-solid-state hybrid supercapacitor was fabricated using PDA@CMS as a positive electrode and radish-derived carbon as a negative electrode with gel-type electrolyte, which delivered the power and energy densities of 7750 W kg−1 and 21.85 Wh kg−1, respectively with superior cycling stability (96.5 % capacitance retention over 10,000 cycles).
期刊介绍:
Journal of energy storage focusses on all aspects of energy storage, in particular systems integration, electric grid integration, modelling and analysis, novel energy storage technologies, sizing and management strategies, business models for operation of storage systems and energy storage developments worldwide.