残余碳支撑的 δ-MnO2 作为高比容量锌离子水电池的阴极

IF 8.9 2区 工程技术 Q1 ENERGY & FUELS
Zhixiong Li , Chengli Wu , Lirui Mao , ChengJie Yin
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引用次数: 0

摘要

锰基氧化物是一种很有前途的水性锌离子电池(AZIB)阴极材料,但由于其反应动力学慢、比容量低,因此面临着诸多限制。因此,本研究采用两步酸浸法从煤气化细渣中提取残碳(RC),并利用水热法在 RC 表面生长二氧化锰纳米花。通过调整 RC 的加入量,实现了最佳的负载状态和团簇形态。与 δ-MnO2 相比,该复合材料在 0.2 A g-1 的条件下显示出 531 mAh g-1 的高比容量。复合材料的表征和电化学动力学分析表明,独特的纳米花形态和 RC 提供了更多的活性位点,缩短了离子传输路径,提高了离子扩散速率。此外,RC 的加入还提供了更多的氧空位,提高了比容量,改善了反应动力学。通过对阴极材料充放电机理的研究发现,该复合材料不仅有利于 H+/Zn2+ 离子的插入/萃取,还能增强循环过程中的结晶稳定性。这项研究为开发高性能 AZIBs 阴极材料提供了一种新方法,并为利用煤基固体废弃物开辟了一条新途径。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Residual-carbon-supported δ-MnO2 as cathodes for aqueous zinc ion batteries with high specific capacity

Residual-carbon-supported δ-MnO2 as cathodes for aqueous zinc ion batteries with high specific capacity
Manganese-based oxides, as promising cathode materials for aqueous zinc-ion batteries (AZIBs), face limitations due to their slow reaction kinetics and low specific capacity. Therefore, this study employed a two-step acid leaching method to extract residual carbon (RC) from coal gasification fine slag and used a hydrothermal method to grow manganese dioxide nanoflowers on the RC surface. By adjusting the amount of RC incorporated, the optimal loading state and cluster morphology were achieved. Compared with the δ-MnO2, the composite material exhibited a high specific capacity of 531 mAh g−1 at 0.2 A g−1. Characterization and electrochemical kinetic analysis of the composite material revealed that the unique nanoflower morphology and RC provided more active sites, shortened ion transport pathways, and increased ion diffusion rates. Furthermore, the inclusion of RC provided more oxygen vacancies, enhancing the specific capacity, and improved the reaction kinetics. Through studies on the charge and discharge mechanisms of the cathode material, it was found that the composite not only facilitated the insertion/extraction of H+/Zn2+ ions but also enhanced crystallization stability during cycling. This research offers a new approach for developing high-performance AZIBs cathode materials and opens a new avenue for utilizing coal-based solid waste.
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来源期刊
Journal of energy storage
Journal of energy storage Energy-Renewable Energy, Sustainability and the Environment
CiteScore
11.80
自引率
24.50%
发文量
2262
审稿时长
69 days
期刊介绍: Journal of energy storage focusses on all aspects of energy storage, in particular systems integration, electric grid integration, modelling and analysis, novel energy storage technologies, sizing and management strategies, business models for operation of storage systems and energy storage developments worldwide.
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