用于超薄电磁波吸收的逐层密集堆叠 SnO2/rGO 复合材料

IF 4.9 2区 化学 Q2 CHEMISTRY, PHYSICAL
Xuji Zhang , Yishan Wang , Dongdong Liu , Yao Wang , Xueqian Zhang , Xiaoxiao Huang
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引用次数: 0

摘要

二氧化锡(SnO2)作为一种极化可调、介质损耗高、绿色环保的易调介电材料,已成为制造高效微波吸收器的新选择。然而,二氧化锡的单一衰减机制导致其在有效吸收电磁波方面存在局限性。本研究成功合成了具有逐层致密堆积结构的二氧化锡/石墨烯复合材料。研究进一步发现,二氧化锡颗粒在石墨烯薄片中的成功负载形成了丰富的异质界面和缺陷,从而改善了二氧化锡/石墨烯复合材料的界面/缺陷极化。逐层致密堆叠结构增强了材料内部电磁波的多重反射/散射,从而加强了电磁波损耗。此外,层与层之间的紧密连接有助于电子的快速传输,确保了复合材料良好的传导损耗。传导损耗和极化损耗之间的良好协同作用使复合材料实现了优异的微波吸收性能,逐层密集堆叠结构确保了材料的薄厚度,最小反射损耗为-41.79 dB,有效吸收带宽为 4.16 GHz,仅为 2.0 mm。此外,战斗机雷达截面模拟突出了 SnO2/rGO 复合材料在雷达隐形应用方面的潜力。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Layer-by-layer densely stacked SnO2/rGO composites for ultrathin electromagnetic wave absorption
Tin dioxide (SnO2), as an easily tunable dielectric material with adjustable polarisation, high dielectric loss and green environment, has become a new choice for building efficient microwave absorbers. However, the single attenuation mechanism of SnO2 causes its limitation in the effective absorption of electromagnetic waves. In this study, tin dioxide/graphene composites with layer-by-layer dense stacking structure were successfully synthesised. It was further found that the successful loading of SnO2 particles in graphene flakes formed abundant heterogeneous interfaces and defects, which improved the interface/defect polarisation of the SnO2/rGO composites. The layer-by-layer dense stacked structure enhances the multiple reflection/scattering of electromagnetic waves inside the material, which strengthens the electromagnetic wave loss. In addition, the close connection between the layers helps the rapid electron transport and ensures the good conduction loss of the composite. The excellent synergy between conduction loss and polarisation loss enables the composites to achieve excellent microwave absorption performance, and the layer-by-layer dense stacking structure ensures the thin thickness of the material, with a minimum reflection loss of −41.79 dB and an effective absorption bandwidth of 4.16 GHz at only 2.0 mm. In addition, fighter radar cross section simulations highlight the potential of SnO2/rGO composites for radar stealth applications.
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来源期刊
CiteScore
8.70
自引率
9.60%
发文量
2421
审稿时长
56 days
期刊介绍: Colloids and Surfaces A: Physicochemical and Engineering Aspects is an international journal devoted to the science underlying applications of colloids and interfacial phenomena. The journal aims at publishing high quality research papers featuring new materials or new insights into the role of colloid and interface science in (for example) food, energy, minerals processing, pharmaceuticals or the environment.
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