Peng Wang , Xueqian Zhang , Bin Zhou , Wencai Zhang , Fanpeng Meng , Chuncheng Wei , Lijuan Zhou , Guangwu Wen , Yishan Wang
{"title":"用于增强苯酚臭氧反应的 CeMnOX 催化剂:性能评估和机理研究","authors":"Peng Wang , Xueqian Zhang , Bin Zhou , Wencai Zhang , Fanpeng Meng , Chuncheng Wei , Lijuan Zhou , Guangwu Wen , Yishan Wang","doi":"10.1016/j.colsurfa.2024.135771","DOIUrl":null,"url":null,"abstract":"<div><div>In order to enhance the catalytic activity and stability of transition metal catalysts in heterogeneous ozonation and effectively treat phenol-containing wastewater, we synthesized a cerium-manganese composite catalyst (CeMnO<sub>X</sub>) using hydrothermal and calcination methods. The results show that Mn atoms doped into the CeO<sub>2</sub> lattice form CeMnO<sub>X</sub> solid solution, which possesses abundant surface defects. The large specific surface area and pore volume of the catalyst favor the exposure of active sites. The CeMnO<sub>X</sub> catalyst contains rich redox pairs and a high amount of chemisorbed oxygen, with numerous oxygen vacancies serving as reactive sites, thereby improving catalytic performance. Degradation experiments demonstrated that the CeMnO<sub>X</sub> catalyst achieved nearly 100 % COD removal within 30 min during catalytic ozonation of phenol, with a significantly higher catalytic efficiency than pure CeO<sub>2</sub> or MnO<sub>X</sub>. Among them, Ce<sub>0.3</sub>Mn<sub>0.7</sub>O<sub>X</sub> exhibited the best performance due to the presence of both the CeMnO<sub>X</sub> solid solution and MnO<sub>X</sub> phases. The combined effect of oxygen vacancies and the synergistic interaction between Ce and Mn is critical to the exceptional catalytic activity of the CeMnO<sub>X</sub> catalyst.</div></div>","PeriodicalId":278,"journal":{"name":"Colloids and Surfaces A: Physicochemical and Engineering Aspects","volume":"706 ","pages":"Article 135771"},"PeriodicalIF":4.9000,"publicationDate":"2024-11-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"CeMnOX catalysts for enhanced ozonation of phenol: Performance evaluation and mechanism investigation\",\"authors\":\"Peng Wang , Xueqian Zhang , Bin Zhou , Wencai Zhang , Fanpeng Meng , Chuncheng Wei , Lijuan Zhou , Guangwu Wen , Yishan Wang\",\"doi\":\"10.1016/j.colsurfa.2024.135771\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>In order to enhance the catalytic activity and stability of transition metal catalysts in heterogeneous ozonation and effectively treat phenol-containing wastewater, we synthesized a cerium-manganese composite catalyst (CeMnO<sub>X</sub>) using hydrothermal and calcination methods. The results show that Mn atoms doped into the CeO<sub>2</sub> lattice form CeMnO<sub>X</sub> solid solution, which possesses abundant surface defects. The large specific surface area and pore volume of the catalyst favor the exposure of active sites. The CeMnO<sub>X</sub> catalyst contains rich redox pairs and a high amount of chemisorbed oxygen, with numerous oxygen vacancies serving as reactive sites, thereby improving catalytic performance. Degradation experiments demonstrated that the CeMnO<sub>X</sub> catalyst achieved nearly 100 % COD removal within 30 min during catalytic ozonation of phenol, with a significantly higher catalytic efficiency than pure CeO<sub>2</sub> or MnO<sub>X</sub>. Among them, Ce<sub>0.3</sub>Mn<sub>0.7</sub>O<sub>X</sub> exhibited the best performance due to the presence of both the CeMnO<sub>X</sub> solid solution and MnO<sub>X</sub> phases. The combined effect of oxygen vacancies and the synergistic interaction between Ce and Mn is critical to the exceptional catalytic activity of the CeMnO<sub>X</sub> catalyst.</div></div>\",\"PeriodicalId\":278,\"journal\":{\"name\":\"Colloids and Surfaces A: Physicochemical and Engineering Aspects\",\"volume\":\"706 \",\"pages\":\"Article 135771\"},\"PeriodicalIF\":4.9000,\"publicationDate\":\"2024-11-15\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Colloids and Surfaces A: Physicochemical and Engineering Aspects\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0927775724026359\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Colloids and Surfaces A: Physicochemical and Engineering Aspects","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0927775724026359","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
CeMnOX catalysts for enhanced ozonation of phenol: Performance evaluation and mechanism investigation
In order to enhance the catalytic activity and stability of transition metal catalysts in heterogeneous ozonation and effectively treat phenol-containing wastewater, we synthesized a cerium-manganese composite catalyst (CeMnOX) using hydrothermal and calcination methods. The results show that Mn atoms doped into the CeO2 lattice form CeMnOX solid solution, which possesses abundant surface defects. The large specific surface area and pore volume of the catalyst favor the exposure of active sites. The CeMnOX catalyst contains rich redox pairs and a high amount of chemisorbed oxygen, with numerous oxygen vacancies serving as reactive sites, thereby improving catalytic performance. Degradation experiments demonstrated that the CeMnOX catalyst achieved nearly 100 % COD removal within 30 min during catalytic ozonation of phenol, with a significantly higher catalytic efficiency than pure CeO2 or MnOX. Among them, Ce0.3Mn0.7OX exhibited the best performance due to the presence of both the CeMnOX solid solution and MnOX phases. The combined effect of oxygen vacancies and the synergistic interaction between Ce and Mn is critical to the exceptional catalytic activity of the CeMnOX catalyst.
期刊介绍:
Colloids and Surfaces A: Physicochemical and Engineering Aspects is an international journal devoted to the science underlying applications of colloids and interfacial phenomena.
The journal aims at publishing high quality research papers featuring new materials or new insights into the role of colloid and interface science in (for example) food, energy, minerals processing, pharmaceuticals or the environment.