{"title":"从天然丝瓜纤维素中提取的磁性多孔嵌钴掺氮生物炭用于高效吸附水中的四环素","authors":"Qinghua Wu, Wenhui Yu, Yancheng Wu, Feng Gan, Xianhua Zeng, Longfei Fan, Zijin Liu, Baoliu Qu","doi":"10.1016/j.colsurfa.2024.135772","DOIUrl":null,"url":null,"abstract":"<div><div>Carbon-based composite materials with high specific surface areas can provide favorable conditions for wastewater treatment. Nevertheless, it remains challenging to sustainably synthesize high-adsorption performance carbon materials on a large scale. Here, we report a facile green method for the scalable synthesis of magnetic porous adsorbents using inexpensive and widely available natural loofah (L) biomass as the carbon precursor. Polydopamine (P) and zeolitic imidazolate framework-67 (ZIF-67) were introduced into the biochar via an in situ self-assembly approach to enable heteroatom doping and increase the specific surface area. After carbonization under a N<sub>2</sub> atmosphere, the nitrogen-doped adsorbent of C-(ZIF-67@P@L) retained a highly interconnected honeycomb-like 3D porous structure with a high specific surface area of 444.59 m<sup>2</sup>/g. Adsorption kinetics and thermodynamics conformed to the pseudo-second-order kinetic and Langmuir isotherm model, with the maximum adsorption capacity estimated at 662.25 mg/g on the basis of the Langmuir isotherm equation. The adsorption mechanism investigation revealed that the adsorption mechanism mainly included electrostatic interactions, π<img>π interactions, hydrogen bonding, and pore filling. Additionally, the adsorbent had good cycle stability and the ability to be magnetically separated from water, making it highly promising for practical wastewater treatment applications.</div></div>","PeriodicalId":278,"journal":{"name":"Colloids and Surfaces A: Physicochemical and Engineering Aspects","volume":"706 ","pages":"Article 135772"},"PeriodicalIF":4.9000,"publicationDate":"2024-11-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Magnetic porous cobalt-embedded nitrogen-doped biochar derived from natural loofah cellulose for efficient adsorption of tetracycline from water\",\"authors\":\"Qinghua Wu, Wenhui Yu, Yancheng Wu, Feng Gan, Xianhua Zeng, Longfei Fan, Zijin Liu, Baoliu Qu\",\"doi\":\"10.1016/j.colsurfa.2024.135772\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Carbon-based composite materials with high specific surface areas can provide favorable conditions for wastewater treatment. Nevertheless, it remains challenging to sustainably synthesize high-adsorption performance carbon materials on a large scale. Here, we report a facile green method for the scalable synthesis of magnetic porous adsorbents using inexpensive and widely available natural loofah (L) biomass as the carbon precursor. Polydopamine (P) and zeolitic imidazolate framework-67 (ZIF-67) were introduced into the biochar via an in situ self-assembly approach to enable heteroatom doping and increase the specific surface area. After carbonization under a N<sub>2</sub> atmosphere, the nitrogen-doped adsorbent of C-(ZIF-67@P@L) retained a highly interconnected honeycomb-like 3D porous structure with a high specific surface area of 444.59 m<sup>2</sup>/g. Adsorption kinetics and thermodynamics conformed to the pseudo-second-order kinetic and Langmuir isotherm model, with the maximum adsorption capacity estimated at 662.25 mg/g on the basis of the Langmuir isotherm equation. The adsorption mechanism investigation revealed that the adsorption mechanism mainly included electrostatic interactions, π<img>π interactions, hydrogen bonding, and pore filling. Additionally, the adsorbent had good cycle stability and the ability to be magnetically separated from water, making it highly promising for practical wastewater treatment applications.</div></div>\",\"PeriodicalId\":278,\"journal\":{\"name\":\"Colloids and Surfaces A: Physicochemical and Engineering Aspects\",\"volume\":\"706 \",\"pages\":\"Article 135772\"},\"PeriodicalIF\":4.9000,\"publicationDate\":\"2024-11-18\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Colloids and Surfaces A: Physicochemical and Engineering Aspects\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0927775724026360\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Colloids and Surfaces A: Physicochemical and Engineering Aspects","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0927775724026360","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
Magnetic porous cobalt-embedded nitrogen-doped biochar derived from natural loofah cellulose for efficient adsorption of tetracycline from water
Carbon-based composite materials with high specific surface areas can provide favorable conditions for wastewater treatment. Nevertheless, it remains challenging to sustainably synthesize high-adsorption performance carbon materials on a large scale. Here, we report a facile green method for the scalable synthesis of magnetic porous adsorbents using inexpensive and widely available natural loofah (L) biomass as the carbon precursor. Polydopamine (P) and zeolitic imidazolate framework-67 (ZIF-67) were introduced into the biochar via an in situ self-assembly approach to enable heteroatom doping and increase the specific surface area. After carbonization under a N2 atmosphere, the nitrogen-doped adsorbent of C-(ZIF-67@P@L) retained a highly interconnected honeycomb-like 3D porous structure with a high specific surface area of 444.59 m2/g. Adsorption kinetics and thermodynamics conformed to the pseudo-second-order kinetic and Langmuir isotherm model, with the maximum adsorption capacity estimated at 662.25 mg/g on the basis of the Langmuir isotherm equation. The adsorption mechanism investigation revealed that the adsorption mechanism mainly included electrostatic interactions, ππ interactions, hydrogen bonding, and pore filling. Additionally, the adsorbent had good cycle stability and the ability to be magnetically separated from water, making it highly promising for practical wastewater treatment applications.
期刊介绍:
Colloids and Surfaces A: Physicochemical and Engineering Aspects is an international journal devoted to the science underlying applications of colloids and interfacial phenomena.
The journal aims at publishing high quality research papers featuring new materials or new insights into the role of colloid and interface science in (for example) food, energy, minerals processing, pharmaceuticals or the environment.