Fausto Viteri, Katiuska Alexandrino, Ángela Millera, Rafael Bilbao, María U. Alzueta
{"title":"二甲氧基甲烷(DMM)热解过程中形成的多环芳烃。与其他含氧添加剂的比较","authors":"Fausto Viteri, Katiuska Alexandrino, Ángela Millera, Rafael Bilbao, María U. Alzueta","doi":"10.1016/j.fuel.2024.133750","DOIUrl":null,"url":null,"abstract":"<div><div>The influence of the temperature (1075 – 1475 K) and inlet concentration of fuel (33,333 and 50,000 ppmv) on the formation of the 16 EPA-priority Polycyclic Aromatic Hydrocarbons (PAH) from the pyrolysis of dimethoxymethane (DMM) was analyzed. PAH were detected in different phases (gas phase, adsorbed on soot, and stuck on the reactor walls) and quantified by gas chromatography-mass spectrometry (GC–MS). Additionally, the toxicity of the PAH samples, expressed as B[<em>a</em>]P-eq, was analyzed in all experiments. A comparison with the results obtained from the pyrolysis of other oxygenated compounds was also performed and similar behaviors were observed. The main results showed that, at low temperatures, the highest concentrations of PAH were found in the gas phase, while at high temperatures were found on soot. For both inlet concentrations of DMM, the light PAH, such as naphthalene and acenaphthylene, were found in major concentrations, in all phases and temperatures. The heavy PAH, such as fluoranthene and pyrene, increased its concentration on soot at highest temperatures. The highest formation of soot was obtained at 1475 K and follows the trend: 2,5DMF < <em>tert</em>-butanol < 2MF < 2butanol < <em>iso</em>-butanol < 1-butanol < ethanol < DMC < DMM. The highest formation of PAH was at 1275 K with the tendency: <em>tert</em>-butanol < 2-butanol < 1-butanol < 2,5DMF < 2MF < <em>iso</em>-butanol < ethanol < DMC < DMM. The highest B[<em>a</em>]P-eq value was found in the pyrolysis of 2,5DMF, and the lowest in the pyrolysis of DMM.</div></div>","PeriodicalId":325,"journal":{"name":"Fuel","volume":"383 ","pages":"Article 133750"},"PeriodicalIF":6.7000,"publicationDate":"2024-11-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Polycyclic aromatic hydrocarbons formed during the pyrolysis of dimethoxymethane (DMM). Comparison with other oxygenated additives\",\"authors\":\"Fausto Viteri, Katiuska Alexandrino, Ángela Millera, Rafael Bilbao, María U. Alzueta\",\"doi\":\"10.1016/j.fuel.2024.133750\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>The influence of the temperature (1075 – 1475 K) and inlet concentration of fuel (33,333 and 50,000 ppmv) on the formation of the 16 EPA-priority Polycyclic Aromatic Hydrocarbons (PAH) from the pyrolysis of dimethoxymethane (DMM) was analyzed. PAH were detected in different phases (gas phase, adsorbed on soot, and stuck on the reactor walls) and quantified by gas chromatography-mass spectrometry (GC–MS). Additionally, the toxicity of the PAH samples, expressed as B[<em>a</em>]P-eq, was analyzed in all experiments. A comparison with the results obtained from the pyrolysis of other oxygenated compounds was also performed and similar behaviors were observed. The main results showed that, at low temperatures, the highest concentrations of PAH were found in the gas phase, while at high temperatures were found on soot. For both inlet concentrations of DMM, the light PAH, such as naphthalene and acenaphthylene, were found in major concentrations, in all phases and temperatures. The heavy PAH, such as fluoranthene and pyrene, increased its concentration on soot at highest temperatures. The highest formation of soot was obtained at 1475 K and follows the trend: 2,5DMF < <em>tert</em>-butanol < 2MF < 2butanol < <em>iso</em>-butanol < 1-butanol < ethanol < DMC < DMM. The highest formation of PAH was at 1275 K with the tendency: <em>tert</em>-butanol < 2-butanol < 1-butanol < 2,5DMF < 2MF < <em>iso</em>-butanol < ethanol < DMC < DMM. The highest B[<em>a</em>]P-eq value was found in the pyrolysis of 2,5DMF, and the lowest in the pyrolysis of DMM.</div></div>\",\"PeriodicalId\":325,\"journal\":{\"name\":\"Fuel\",\"volume\":\"383 \",\"pages\":\"Article 133750\"},\"PeriodicalIF\":6.7000,\"publicationDate\":\"2024-11-27\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Fuel\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0016236124028990\",\"RegionNum\":1,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"ENERGY & FUELS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Fuel","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0016236124028990","RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ENERGY & FUELS","Score":null,"Total":0}
Polycyclic aromatic hydrocarbons formed during the pyrolysis of dimethoxymethane (DMM). Comparison with other oxygenated additives
The influence of the temperature (1075 – 1475 K) and inlet concentration of fuel (33,333 and 50,000 ppmv) on the formation of the 16 EPA-priority Polycyclic Aromatic Hydrocarbons (PAH) from the pyrolysis of dimethoxymethane (DMM) was analyzed. PAH were detected in different phases (gas phase, adsorbed on soot, and stuck on the reactor walls) and quantified by gas chromatography-mass spectrometry (GC–MS). Additionally, the toxicity of the PAH samples, expressed as B[a]P-eq, was analyzed in all experiments. A comparison with the results obtained from the pyrolysis of other oxygenated compounds was also performed and similar behaviors were observed. The main results showed that, at low temperatures, the highest concentrations of PAH were found in the gas phase, while at high temperatures were found on soot. For both inlet concentrations of DMM, the light PAH, such as naphthalene and acenaphthylene, were found in major concentrations, in all phases and temperatures. The heavy PAH, such as fluoranthene and pyrene, increased its concentration on soot at highest temperatures. The highest formation of soot was obtained at 1475 K and follows the trend: 2,5DMF < tert-butanol < 2MF < 2butanol < iso-butanol < 1-butanol < ethanol < DMC < DMM. The highest formation of PAH was at 1275 K with the tendency: tert-butanol < 2-butanol < 1-butanol < 2,5DMF < 2MF < iso-butanol < ethanol < DMC < DMM. The highest B[a]P-eq value was found in the pyrolysis of 2,5DMF, and the lowest in the pyrolysis of DMM.
期刊介绍:
The exploration of energy sources remains a critical matter of study. For the past nine decades, fuel has consistently held the forefront in primary research efforts within the field of energy science. This area of investigation encompasses a wide range of subjects, with a particular emphasis on emerging concerns like environmental factors and pollution.