{"title":"镍铁氧体作为酒精氧化反应的高效电催化剂","authors":"P.C. Nagajyothi , K. Muniratnam , Jaesool Shim","doi":"10.1016/j.matlet.2024.137752","DOIUrl":null,"url":null,"abstract":"<div><div>Nickel ferrite (NiFe<sub>2</sub>O<sub>4</sub>) electrocatalyst was synthesized via a simple, rapid hydrothermal method. The electrocatalyst’s composition and structure were analyzed using various techniques. The electrocatalytic activity of NiFe<sub>2</sub>O<sub>4</sub> toward the oxidation of alcohols such as methanol, ethanol, propanol, and isopropanol in an alkaline medium was studied using cyclic voltammetry, linear scan voltammetry, and electrochemical impedance spectroscopy. The methanol oxidation reaction (MOR) exhibited a lower overpotential than the other alcohol oxidation reactions, suggesting that NiFe<sub>2</sub>O<sub>4</sub> is an excellent catalyst for MOR.</div></div>","PeriodicalId":384,"journal":{"name":"Materials Letters","volume":"381 ","pages":"Article 137752"},"PeriodicalIF":2.7000,"publicationDate":"2024-11-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Nickel ferrite as an efficient electrocatalyst for alcohol oxidation reactions\",\"authors\":\"P.C. Nagajyothi , K. Muniratnam , Jaesool Shim\",\"doi\":\"10.1016/j.matlet.2024.137752\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Nickel ferrite (NiFe<sub>2</sub>O<sub>4</sub>) electrocatalyst was synthesized via a simple, rapid hydrothermal method. The electrocatalyst’s composition and structure were analyzed using various techniques. The electrocatalytic activity of NiFe<sub>2</sub>O<sub>4</sub> toward the oxidation of alcohols such as methanol, ethanol, propanol, and isopropanol in an alkaline medium was studied using cyclic voltammetry, linear scan voltammetry, and electrochemical impedance spectroscopy. The methanol oxidation reaction (MOR) exhibited a lower overpotential than the other alcohol oxidation reactions, suggesting that NiFe<sub>2</sub>O<sub>4</sub> is an excellent catalyst for MOR.</div></div>\",\"PeriodicalId\":384,\"journal\":{\"name\":\"Materials Letters\",\"volume\":\"381 \",\"pages\":\"Article 137752\"},\"PeriodicalIF\":2.7000,\"publicationDate\":\"2024-11-22\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Materials Letters\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0167577X24018925\",\"RegionNum\":4,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Materials Letters","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0167577X24018925","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
Nickel ferrite as an efficient electrocatalyst for alcohol oxidation reactions
Nickel ferrite (NiFe2O4) electrocatalyst was synthesized via a simple, rapid hydrothermal method. The electrocatalyst’s composition and structure were analyzed using various techniques. The electrocatalytic activity of NiFe2O4 toward the oxidation of alcohols such as methanol, ethanol, propanol, and isopropanol in an alkaline medium was studied using cyclic voltammetry, linear scan voltammetry, and electrochemical impedance spectroscopy. The methanol oxidation reaction (MOR) exhibited a lower overpotential than the other alcohol oxidation reactions, suggesting that NiFe2O4 is an excellent catalyst for MOR.
期刊介绍:
Materials Letters has an open access mirror journal Materials Letters: X, sharing the same aims and scope, editorial team, submission system and rigorous peer review.
Materials Letters is dedicated to publishing novel, cutting edge reports of broad interest to the materials community. The journal provides a forum for materials scientists and engineers, physicists, and chemists to rapidly communicate on the most important topics in the field of materials.
Contributions include, but are not limited to, a variety of topics such as:
• Materials - Metals and alloys, amorphous solids, ceramics, composites, polymers, semiconductors
• Applications - Structural, opto-electronic, magnetic, medical, MEMS, sensors, smart
• Characterization - Analytical, microscopy, scanning probes, nanoscopic, optical, electrical, magnetic, acoustic, spectroscopic, diffraction
• Novel Materials - Micro and nanostructures (nanowires, nanotubes, nanoparticles), nanocomposites, thin films, superlattices, quantum dots.
• Processing - Crystal growth, thin film processing, sol-gel processing, mechanical processing, assembly, nanocrystalline processing.
• Properties - Mechanical, magnetic, optical, electrical, ferroelectric, thermal, interfacial, transport, thermodynamic
• Synthesis - Quenching, solid state, solidification, solution synthesis, vapor deposition, high pressure, explosive