{"title":"通过将锐钛矿二氧化钛配置成双连续介观结构实现电子结构调制","authors":"Ying-Hao Lu, Bor Kae Chang, Yi-Fan Chen","doi":"10.1016/j.jtice.2024.105829","DOIUrl":null,"url":null,"abstract":"<div><h3>Background</h3><div>Configuring TiO<sub>2</sub> into bicontinuous mesostructures greatly enhances its photocatalytic efficiency. While this enhancement is commonly attributed to the expanded surface area, it has become apparent that the surface-area expansion alone cannot fully explain the efficiency enhancement.</div></div><div><h3>Methods</h3><div>Investigating additional factors becomes imperative and will be conducive to realizing further efficacy enhancement for photocatalysts. This paper presents spectroscopic and density functional theory approaches in finding additional reasons for the increased photocatalytic activity.</div></div><div><h3>Significant Findings</h3><div>Results show that the enhanced efficacy resulting from mesostructuring is not solely due to an expansion in surface area but also stems from modulations in the TiO<sub>2</sub> electronic structure. The finding not only advances current understanding of mesostructuring-induced effects on metal-oxide semiconductors but also introduces an alternative avenue for fine-tuning a material electronic structure.</div></div>","PeriodicalId":381,"journal":{"name":"Journal of the Taiwan Institute of Chemical Engineers","volume":"167 ","pages":""},"PeriodicalIF":5.5000,"publicationDate":"2024-11-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Electronic structure modulation from configuring anatase TiO2 into a bicontinuous mesostructure\",\"authors\":\"Ying-Hao Lu, Bor Kae Chang, Yi-Fan Chen\",\"doi\":\"10.1016/j.jtice.2024.105829\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><h3>Background</h3><div>Configuring TiO<sub>2</sub> into bicontinuous mesostructures greatly enhances its photocatalytic efficiency. While this enhancement is commonly attributed to the expanded surface area, it has become apparent that the surface-area expansion alone cannot fully explain the efficiency enhancement.</div></div><div><h3>Methods</h3><div>Investigating additional factors becomes imperative and will be conducive to realizing further efficacy enhancement for photocatalysts. This paper presents spectroscopic and density functional theory approaches in finding additional reasons for the increased photocatalytic activity.</div></div><div><h3>Significant Findings</h3><div>Results show that the enhanced efficacy resulting from mesostructuring is not solely due to an expansion in surface area but also stems from modulations in the TiO<sub>2</sub> electronic structure. The finding not only advances current understanding of mesostructuring-induced effects on metal-oxide semiconductors but also introduces an alternative avenue for fine-tuning a material electronic structure.</div></div>\",\"PeriodicalId\":381,\"journal\":{\"name\":\"Journal of the Taiwan Institute of Chemical Engineers\",\"volume\":\"167 \",\"pages\":\"\"},\"PeriodicalIF\":5.5000,\"publicationDate\":\"2024-11-28\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of the Taiwan Institute of Chemical Engineers\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S1876107024004875\",\"RegionNum\":3,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"ENGINEERING, CHEMICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of the Taiwan Institute of Chemical Engineers","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1876107024004875","RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"ENGINEERING, CHEMICAL","Score":null,"Total":0}
Electronic structure modulation from configuring anatase TiO2 into a bicontinuous mesostructure
Background
Configuring TiO2 into bicontinuous mesostructures greatly enhances its photocatalytic efficiency. While this enhancement is commonly attributed to the expanded surface area, it has become apparent that the surface-area expansion alone cannot fully explain the efficiency enhancement.
Methods
Investigating additional factors becomes imperative and will be conducive to realizing further efficacy enhancement for photocatalysts. This paper presents spectroscopic and density functional theory approaches in finding additional reasons for the increased photocatalytic activity.
Significant Findings
Results show that the enhanced efficacy resulting from mesostructuring is not solely due to an expansion in surface area but also stems from modulations in the TiO2 electronic structure. The finding not only advances current understanding of mesostructuring-induced effects on metal-oxide semiconductors but also introduces an alternative avenue for fine-tuning a material electronic structure.
期刊介绍:
Journal of the Taiwan Institute of Chemical Engineers (formerly known as Journal of the Chinese Institute of Chemical Engineers) publishes original works, from fundamental principles to practical applications, in the broad field of chemical engineering with special focus on three aspects: Chemical and Biomolecular Science and Technology, Energy and Environmental Science and Technology, and Materials Science and Technology. Authors should choose for their manuscript an appropriate aspect section and a few related classifications when submitting to the journal online.