与水滴排列相关的稳定油包水乳液的流变特性

IF 4.9 2区 化学 Q2 CHEMISTRY, PHYSICAL
Natan Augusto Vieira Bulgarelli , Letícia Bizarre , William Monte Verde , Andrey Felipe Casas Pulido , Marcelo Souza de Castro
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引用次数: 0

摘要

油包水型乳化液是一种在石油生产过程中可能出现的流动形态,由于其流变行为而产生流动保证问题。除了有效粘度会随着含水量的增加而增加之外,乳状液的流变行为还与流体的物理化学性质和表面活性剂的存在有关。本研究对多级离心泵剪切形成的稳定油包水型乳化液的流变学进行了研究。所分析的乳状液由矿物油、SPAN 80 和自来水组成,并适用于不同的截水量和温度。对乳液流动曲线进行了剪切速率滞后分析,以分析其流变行为。通过分析,研究了基于佩克莱特数的水滴排列的稳态剪切应力条件。此外,还使用流变仪上的显微镜观察了流动曲线采集过程中的液滴排列情况。为了研究流变过程中乳液的团聚力学,我们根据临界剪切应力、液滴雷诺数和不同温度下的切水量,提出了分离悬浮液滴和团聚液滴的表面边界。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Rheological behavior of the stable water-in-oil emulsion associated to water droplets arrangement

Rheological behavior of the stable water-in-oil emulsion associated to water droplets arrangement
Water-in-oil emulsion is a flow pattern that may occur during the oil production and generate flow assurance issues due to its rheological behavior. In addition to the increase of effective viscosity with water content increment, the emulsion has a complex rheological behavior regarding the fluid’s physicochemical properties, and surfactant presence. In this work, the rheology of stable water-in-oil emulsion formed by the shearing of a multistage centrifugal pump is investigated. The emulsion analyzed was composed of a mineral oil, SPAN 80 and tap water for different water cut and temperatures. The shear rate hysteresis analysis on emulsion flow curve were performed to analyze the rheological behavior. From this analysis, the steady-state shear stress condition was investigated regarding water droplet arrangement based on the Peclet number. Furthermore, the droplet arrangement was observed during acquisition of flow curve using a microscopy coupled on rheometer. To investigate the clustering mechanics in emulsion during rheometry, we present a surface boundary to separate the suspending and clustering droplets based on critical shear stress, droplet Reynolds number, and the water cut for different temperatures.
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来源期刊
CiteScore
8.70
自引率
9.60%
发文量
2421
审稿时长
56 days
期刊介绍: Colloids and Surfaces A: Physicochemical and Engineering Aspects is an international journal devoted to the science underlying applications of colloids and interfacial phenomena. The journal aims at publishing high quality research papers featuring new materials or new insights into the role of colloid and interface science in (for example) food, energy, minerals processing, pharmaceuticals or the environment.
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