K. V. Kavya, Dhanaprabhu Pattappan, Raju Suresh Kumar, Sivalingam Ramesh, Kavitha Thangavelu, R. T. Rajendra Kumar, Yuvaraj Haldorai
{"title":"金纳米颗粒锚定胺功能化镍金属有机框架复合材料,用于太阳光辅助高效降解玫瑰红染料和还原 Cr(VI)","authors":"K. V. Kavya, Dhanaprabhu Pattappan, Raju Suresh Kumar, Sivalingam Ramesh, Kavitha Thangavelu, R. T. Rajendra Kumar, Yuvaraj Haldorai","doi":"10.1007/s10854-024-13897-3","DOIUrl":null,"url":null,"abstract":"<div><p>In this report, the photodegradation of rose bengal dye (RB) and reduction of Cr(VI) was performed under solar light using a composite composed of amine-functionalized nickel metal–organic framework (Ni-MOF) and gold (Au). The morphological study revealed that the Ni-MOF surface was embellished with Au nanoparticles that had a mean size of less than 10 nm. The composite photocatalyst exhibited a reduction efficiency of 82% for Cr(VI) and degradation of 88% for RB dye. An experiment investigating radical scavenging confirmed that the production of superoxide radicals was the primary cause of the degradation of RB. The cyclic stability test revealed that the degrading efficiency of RB did not see a significant decline after seven consecutive cycles. The results highlight the favorable photocatalytic characteristics of the Ni-MOF/Au composite, indicating its potential use in environmental remediation.</p></div>","PeriodicalId":646,"journal":{"name":"Journal of Materials Science: Materials in Electronics","volume":"35 34","pages":""},"PeriodicalIF":2.8000,"publicationDate":"2024-11-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Gold nanoparticles anchored amine-functionalized nickel metal–organic framework composite for efficient solar light-assisted degradation of rose bengal dye and Cr(VI) reduction\",\"authors\":\"K. V. Kavya, Dhanaprabhu Pattappan, Raju Suresh Kumar, Sivalingam Ramesh, Kavitha Thangavelu, R. T. Rajendra Kumar, Yuvaraj Haldorai\",\"doi\":\"10.1007/s10854-024-13897-3\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>In this report, the photodegradation of rose bengal dye (RB) and reduction of Cr(VI) was performed under solar light using a composite composed of amine-functionalized nickel metal–organic framework (Ni-MOF) and gold (Au). The morphological study revealed that the Ni-MOF surface was embellished with Au nanoparticles that had a mean size of less than 10 nm. The composite photocatalyst exhibited a reduction efficiency of 82% for Cr(VI) and degradation of 88% for RB dye. An experiment investigating radical scavenging confirmed that the production of superoxide radicals was the primary cause of the degradation of RB. The cyclic stability test revealed that the degrading efficiency of RB did not see a significant decline after seven consecutive cycles. The results highlight the favorable photocatalytic characteristics of the Ni-MOF/Au composite, indicating its potential use in environmental remediation.</p></div>\",\"PeriodicalId\":646,\"journal\":{\"name\":\"Journal of Materials Science: Materials in Electronics\",\"volume\":\"35 34\",\"pages\":\"\"},\"PeriodicalIF\":2.8000,\"publicationDate\":\"2024-11-26\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Materials Science: Materials in Electronics\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s10854-024-13897-3\",\"RegionNum\":4,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"ENGINEERING, ELECTRICAL & ELECTRONIC\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Materials Science: Materials in Electronics","FirstCategoryId":"5","ListUrlMain":"https://link.springer.com/article/10.1007/s10854-024-13897-3","RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ENGINEERING, ELECTRICAL & ELECTRONIC","Score":null,"Total":0}
Gold nanoparticles anchored amine-functionalized nickel metal–organic framework composite for efficient solar light-assisted degradation of rose bengal dye and Cr(VI) reduction
In this report, the photodegradation of rose bengal dye (RB) and reduction of Cr(VI) was performed under solar light using a composite composed of amine-functionalized nickel metal–organic framework (Ni-MOF) and gold (Au). The morphological study revealed that the Ni-MOF surface was embellished with Au nanoparticles that had a mean size of less than 10 nm. The composite photocatalyst exhibited a reduction efficiency of 82% for Cr(VI) and degradation of 88% for RB dye. An experiment investigating radical scavenging confirmed that the production of superoxide radicals was the primary cause of the degradation of RB. The cyclic stability test revealed that the degrading efficiency of RB did not see a significant decline after seven consecutive cycles. The results highlight the favorable photocatalytic characteristics of the Ni-MOF/Au composite, indicating its potential use in environmental remediation.
期刊介绍:
The Journal of Materials Science: Materials in Electronics is an established refereed companion to the Journal of Materials Science. It publishes papers on materials and their applications in modern electronics, covering the ground between fundamental science, such as semiconductor physics, and work concerned specifically with applications. It explores the growth and preparation of new materials, as well as their processing, fabrication, bonding and encapsulation, together with the reliability, failure analysis, quality assurance and characterization related to the whole range of applications in electronics. The Journal presents papers in newly developing fields such as low dimensional structures and devices, optoelectronics including III-V compounds, glasses and linear/non-linear crystal materials and lasers, high Tc superconductors, conducting polymers, thick film materials and new contact technologies, as well as the established electronics device and circuit materials.