通过 P-N 偶联实现膦酰胺和膦酰胺酸盐的流动电合成†。

IF 9.3 1区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY

Green Chemistry Pub Date : 2024-10-22 DOI:10.1039/d4gc04450a

Tribani Boruah , Ren Ishizeki , Alberto Roldan , Rebecca L. Melen , Thomas Wirth

引用次数: 0

摘要

针对 P-N 和 P-O 氧化偶联，我们开发了一种在温和反应条件下运行的稳健的流动电化学方法。使用恒电位和恒电流电解来研究反应物的氧化还原行为，在各种化学背景下展示了广泛的底物范围（47 个实例，收率高达 85%）。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Flow electrosynthesis of phosphinamides and phosphoramidates through P–N coupling†

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Flow electrosynthesis of phosphinamides and phosphoramidates through P–N coupling†

A robust flow electrochemical methodology operating under mild reaction conditions for P–N and P–O oxidative coupling has been developed. Potentiostatic and galvanostatic electrolyses were used to investigate reactant redox behaviour, showcasing a broad substrate scope (47 examples, up to 85% yield) across various chemical contexts.

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来源期刊

Green Chemistry 化学-化学综合

CiteScore

16.10

自引率

7.10%

发文量

677

审稿时长

1.4 months

期刊介绍： Green Chemistry is a journal that provides a unique forum for the publication of innovative research on the development of alternative green and sustainable technologies. The scope of Green Chemistry is based on the definition proposed by Anastas and Warner (Green Chemistry: Theory and Practice, P T Anastas and J C Warner, Oxford University Press, Oxford, 1998), which defines green chemistry as the utilisation of a set of principles that reduces or eliminates the use or generation of hazardous substances in the design, manufacture and application of chemical products. Green Chemistry aims to reduce the environmental impact of the chemical enterprise by developing a technology base that is inherently non-toxic to living things and the environment. The journal welcomes submissions on all aspects of research relating to this endeavor and publishes original and significant cutting-edge research that is likely to be of wide general appeal. For a work to be published, it must present a significant advance in green chemistry, including a comparison with existing methods and a demonstration of advantages over those methods.