"生命之树":猴面包树种子提取的生物炭如何通过去除重金属(铁)为贫困社区带来水安全--可持续发展目标 6

IF 3.5 Q3 ENGINEERING, ENVIRONMENTAL
Magdalena J. Mkelemi, Grite N. Mwaijengo and Mwemezi J. Rwiza
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引用次数: 0

摘要

异常巨大的猴面包树(Adansonia digitata)通常被称为 "生命之树",因为它能够为干旱地区的人类和动物提供食物、水、住所和传统医药。这种特殊的树木是非洲热带稀树草原的标志,吸引了全球研究界的关注。本研究调查了从猴面包树种子中提取的生物炭去除地下水中金属离子的潜力。在 700 °C 下制备的生物炭呈现出独特的表面形态,具有较深的空隙和不同的结构,这表明生物炭的表面积增大,为吸附创造了有利条件。SEM-EDX 分析证实了元素组成,碳是主要元素。此外,XRD 分析表明其为非晶态结构,增强了对重金属离子的吸附能力。此外,BET 分析表明,该材料具有显著的表面积(1386.704 m2 g-1)和清晰的孔隙,强调了其去除金属离子的潜力。本研究选择的金属离子是铁,因为研究区内铁离子含量丰富,而且社区需要经济实惠的技术来解决铁离子存在导致的红褐色地下水变色问题。在批处理模式平衡研究中,研究了 pH 值、接触时间、吸附剂粒度、吸附剂剂量、溶液温度和初始金属离子浓度的影响。在中性 pH 值条件下,出现了最佳 pH 值金属离子去除率,接触时间(最长 120 分钟)和吸附剂剂量增加时,去除率更高。使用 Langmuir 和 Freundlich 模型建立的吸附等温线模型显示了良好的吸附效果,其中 Freundlich 模型的拟合效果稍好。总之,猴面包树种子衍生的生物炭作为一种高效、可持续的吸附剂,在去除地下水中的金属离子方面表现出了巨大的潜力。建议进一步探索,包括开发活性炭和实地应用,以全面了解和切实优化这种材料去除金属离子的能力。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

“Tree of life”: how baobab seed-derived biochar could lead to water safety for underprivileged communities through heavy metal (Fe) removal – SDG 6

“Tree of life”: how baobab seed-derived biochar could lead to water safety for underprivileged communities through heavy metal (Fe) removal – SDG 6

The abnormally gigantic baobab tree (Adansonia digitata) is often referred to as the “Tree of Life” due to its ability to provide food, water, shelter, and traditional medicine for both humans and animals in arid regions. This special tree is a landmark of Africa's savanna and has attracted the attention of the global research community. This study investigated the potential of biochar derived from baobab seeds for the removal of metallic ions from groundwater. The biochar, prepared at 700 °C, exhibited a unique surface morphology with deep voids and varied structures, suggesting increased surface area and favorable conditions for adsorption. SEM-EDX analyses confirmed the elemental composition, with carbon being the predominant element. Furthermore, XRD analysis indicated an amorphous structure, enhancing adsorption capacity for heavy metal ions. Additionally, BET analysis revealed a significant surface area (1386.704 m2 g−1) and well-defined pores, emphasizing the material's potential for metallic ion removal. The metallic ion of choice for this research was Fe because of its abundance in the study area and the community's need for affordable technology for discoloration of reddish-brown groundwater caused by Fe ion presence. In the batch mode equilibrium studies, the effect of pH, contact time, adsorbent particle size, adsorbent dose, solution temperature, and initial metal ion concentration was investigated. Optimal pH metallic ion removal occurred under neutral pH conditions, with higher removal efficiency observed at increased contact time (up to 120 min) and adsorbent doses. Adsorption isotherm modeling using Langmuir and Freundlich models indicated favorable adsorption, with the Freundlich model providing a slightly better fit. In conclusion, baobab seed-derived biochar demonstrated promising potential as an efficient and sustainable adsorbent for metal ion removal from groundwater. Further exploration, including the development of activated carbon and field applications, is recommended for a comprehensive understanding and practical optimization of this material's capabilities for metal ion removal.

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