封面专题：二酰甲酰胺作为 "绿色 "rWGS 反应背景下超纯 CO 的安全储备和室温来源（ChemSusChem 22/2024）

IF 7.5 2区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY

ChemSusChem Pub Date : 2024-11-25 DOI:10.1002/cssc.202482202

Royel Hurtado, Lisha Lou, Lukas Klerner, Iman Dindarloo Inaloo, Frank W. Heineman, Sjoerd Harder, Günter Schmid, Romano Dorta

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引用次数: 0

摘要

封面特写展示了二芳基甲酰胺的无溶剂催化脱羰基反应如何产生纯度极高的一氧化碳，并使其成为理想的一氧化碳固态贮存器/载体。用甲酸/三乙胺共沸物将回收的二芳基甲胺甲酰化成甲酰胺，规模为 30-100 克。更多信息可参阅 I. Dindarloo Inaloo、R. Dorta 及合作者的研究文章。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Cover Feature: Diarylformamides as a Safe Reservoir and Room Temperature Source of Ultra-Pure CO in the Context of a ‘Green’ rWGS Reaction (ChemSusChem 22/2024)

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Cover Feature: Diarylformamides as a Safe Reservoir and Room Temperature Source of Ultra-Pure CO in the Context of a ‘Green’ rWGS Reaction (ChemSusChem 22/2024)

The Cover Feature shows how the solvent-free catalytic decarbonylation of diarylformamides affords very pure CO and makes them ideal solid-state reservoirs/vectors of CO. The recovered diarylamines are readily formylated back to the formamides with formic acid/triethylamine azeotrope on 30–100 g scales. More information can be found in the Research Article by I. Dindarloo Inaloo, R. Dorta and co-workers.

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来源期刊

ChemSusChem 化学-化学综合

CiteScore

15.80

自引率

4.80%

发文量

555

审稿时长

1.8 months

期刊介绍： ChemSusChem Impact Factor (2016): 7.226 Scope: Interdisciplinary journal Focuses on research at the interface of chemistry and sustainability Features the best research on sustainability and energy Areas Covered: Chemistry Materials Science Chemical Engineering Biotechnology