Cheng Ouyang , Shaoping Wu , Guoyao Li , Nan Zhang , Qiwen Chen , Rongzi Zhang , Haidong Sun , Chenglan Zhang , Hezhou Liu , Huanan Duan
{"title":"石榴石基高负载正极锂金属电池的凝胶界面","authors":"Cheng Ouyang , Shaoping Wu , Guoyao Li , Nan Zhang , Qiwen Chen , Rongzi Zhang , Haidong Sun , Chenglan Zhang , Hezhou Liu , Huanan Duan","doi":"10.1016/j.matlet.2024.137729","DOIUrl":null,"url":null,"abstract":"<div><div>Garnet-type electrolytes are ideal for lithium-metal batteries due to their high ionic conductivity and electrochemical stability. However, high interfacial resistance caused by poor contact with electrodes remains a challenge. To address this, we developed a flexible gel interlayer via in-situ polymerization to improve interface contact and reduce impedance. Additionally, a thick cathode with a laser-drilled channel structure was constructed to enhance gel electrolyte penetration and discharge capacity. Consequently, the Li/GEL-LLZTO-GEL/Li symmetric cell achieved a critical current density of 1.5 mA cm<sup>−2</sup> and a reduced interfacial resistance of 134 O at room temperature. The quasi-solid half-cell with the laser-drilled cathode maintained a discharge capacity of 132.4 mAh/g with an active material loading of 13.1 mg cm<sup>−2</sup> after 100 cycles. This work provides a simple and effective method for manufacturing safe and stable lithium metal batteries.</div></div>","PeriodicalId":384,"journal":{"name":"Materials Letters","volume":"380 ","pages":"Article 137729"},"PeriodicalIF":2.7000,"publicationDate":"2024-11-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Gel interface for garnet-based lithium metal batteries with high loading cathode\",\"authors\":\"Cheng Ouyang , Shaoping Wu , Guoyao Li , Nan Zhang , Qiwen Chen , Rongzi Zhang , Haidong Sun , Chenglan Zhang , Hezhou Liu , Huanan Duan\",\"doi\":\"10.1016/j.matlet.2024.137729\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Garnet-type electrolytes are ideal for lithium-metal batteries due to their high ionic conductivity and electrochemical stability. However, high interfacial resistance caused by poor contact with electrodes remains a challenge. To address this, we developed a flexible gel interlayer via in-situ polymerization to improve interface contact and reduce impedance. Additionally, a thick cathode with a laser-drilled channel structure was constructed to enhance gel electrolyte penetration and discharge capacity. Consequently, the Li/GEL-LLZTO-GEL/Li symmetric cell achieved a critical current density of 1.5 mA cm<sup>−2</sup> and a reduced interfacial resistance of 134 O at room temperature. The quasi-solid half-cell with the laser-drilled cathode maintained a discharge capacity of 132.4 mAh/g with an active material loading of 13.1 mg cm<sup>−2</sup> after 100 cycles. This work provides a simple and effective method for manufacturing safe and stable lithium metal batteries.</div></div>\",\"PeriodicalId\":384,\"journal\":{\"name\":\"Materials Letters\",\"volume\":\"380 \",\"pages\":\"Article 137729\"},\"PeriodicalIF\":2.7000,\"publicationDate\":\"2024-11-19\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Materials Letters\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0167577X2401869X\",\"RegionNum\":4,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Materials Letters","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0167577X2401869X","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
Gel interface for garnet-based lithium metal batteries with high loading cathode
Garnet-type electrolytes are ideal for lithium-metal batteries due to their high ionic conductivity and electrochemical stability. However, high interfacial resistance caused by poor contact with electrodes remains a challenge. To address this, we developed a flexible gel interlayer via in-situ polymerization to improve interface contact and reduce impedance. Additionally, a thick cathode with a laser-drilled channel structure was constructed to enhance gel electrolyte penetration and discharge capacity. Consequently, the Li/GEL-LLZTO-GEL/Li symmetric cell achieved a critical current density of 1.5 mA cm−2 and a reduced interfacial resistance of 134 O at room temperature. The quasi-solid half-cell with the laser-drilled cathode maintained a discharge capacity of 132.4 mAh/g with an active material loading of 13.1 mg cm−2 after 100 cycles. This work provides a simple and effective method for manufacturing safe and stable lithium metal batteries.
期刊介绍:
Materials Letters has an open access mirror journal Materials Letters: X, sharing the same aims and scope, editorial team, submission system and rigorous peer review.
Materials Letters is dedicated to publishing novel, cutting edge reports of broad interest to the materials community. The journal provides a forum for materials scientists and engineers, physicists, and chemists to rapidly communicate on the most important topics in the field of materials.
Contributions include, but are not limited to, a variety of topics such as:
• Materials - Metals and alloys, amorphous solids, ceramics, composites, polymers, semiconductors
• Applications - Structural, opto-electronic, magnetic, medical, MEMS, sensors, smart
• Characterization - Analytical, microscopy, scanning probes, nanoscopic, optical, electrical, magnetic, acoustic, spectroscopic, diffraction
• Novel Materials - Micro and nanostructures (nanowires, nanotubes, nanoparticles), nanocomposites, thin films, superlattices, quantum dots.
• Processing - Crystal growth, thin film processing, sol-gel processing, mechanical processing, assembly, nanocrystalline processing.
• Properties - Mechanical, magnetic, optical, electrical, ferroelectric, thermal, interfacial, transport, thermodynamic
• Synthesis - Quenching, solid state, solidification, solution synthesis, vapor deposition, high pressure, explosive