Xuan Wang , Wenjian Huang , Guangzhen Gao, Yubing Yang, Hui Yang, Tingdong Cai
{"title":"用于同时测量火焰中温度、二氧化碳和一氧化碳的 FDM 辅助 OA-CEAS 系统","authors":"Xuan Wang , Wenjian Huang , Guangzhen Gao, Yubing Yang, Hui Yang, Tingdong Cai","doi":"10.1016/j.fuel.2024.133782","DOIUrl":null,"url":null,"abstract":"<div><div>A system based on off-axis cavity enhanced absorption spectroscopy (OA-CEAS) integrated with frequency division multiplexing (FDM)-assisted wavelength modulation spectroscopy (WMS) was developed for simultaneous measurements of temperature, CO<sub>2</sub>, and CO in flames by employing two distributed feedback (DFB) diode lasers at 2.0 µm and 2.3 µm. An integrated cavity with an open-path configuration was made up of two cavity mirrors with a reflectivity of 99.8 %, and an effective optical absorption path length of approximately 5.2 m was achieved within a 6 cm diameter flame region. A CO<sub>2</sub> line pair at 4990.418 cm<sup>−1</sup> and 4990.664 cm<sup>−1</sup>, along with a CO line at 4300.699 cm<sup>−1</sup>, were selected as the measurement targets. The system was initially calibrated in a heated static cell and subsequently tested in C<sub>2</sub>H<sub>4</sub>/air premixed flat flames for six different equivalence ratios. All concentrations measured by the 1<em>f</em>-normalized 2<em>f</em> signals were compared with the results obtained from both the direct absorption signals and simulations based on adiabatic chemical equilibrium calculations using Chemkin. Additionally, the measured temperatures were compared with the thermocouple readings. According to the measurements conducted at representative C<sub>2</sub>H<sub>4</sub> flames with different equivalence ratios, the accuracies for the measurements of temperature, CO<sub>2</sub> concentrations, and CO concentrations were ∼1.062 %, ∼1.082 %, and ∼1.052 %, respectively. All the measurements illustrate the potential of the system for combustion diagnosis.</div></div>","PeriodicalId":325,"journal":{"name":"Fuel","volume":"383 ","pages":"Article 133782"},"PeriodicalIF":6.7000,"publicationDate":"2024-11-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"FDM-assisted OA-CEAS system for simultaneous measurements of temperature, CO2, and CO in flames\",\"authors\":\"Xuan Wang , Wenjian Huang , Guangzhen Gao, Yubing Yang, Hui Yang, Tingdong Cai\",\"doi\":\"10.1016/j.fuel.2024.133782\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>A system based on off-axis cavity enhanced absorption spectroscopy (OA-CEAS) integrated with frequency division multiplexing (FDM)-assisted wavelength modulation spectroscopy (WMS) was developed for simultaneous measurements of temperature, CO<sub>2</sub>, and CO in flames by employing two distributed feedback (DFB) diode lasers at 2.0 µm and 2.3 µm. An integrated cavity with an open-path configuration was made up of two cavity mirrors with a reflectivity of 99.8 %, and an effective optical absorption path length of approximately 5.2 m was achieved within a 6 cm diameter flame region. A CO<sub>2</sub> line pair at 4990.418 cm<sup>−1</sup> and 4990.664 cm<sup>−1</sup>, along with a CO line at 4300.699 cm<sup>−1</sup>, were selected as the measurement targets. The system was initially calibrated in a heated static cell and subsequently tested in C<sub>2</sub>H<sub>4</sub>/air premixed flat flames for six different equivalence ratios. All concentrations measured by the 1<em>f</em>-normalized 2<em>f</em> signals were compared with the results obtained from both the direct absorption signals and simulations based on adiabatic chemical equilibrium calculations using Chemkin. Additionally, the measured temperatures were compared with the thermocouple readings. According to the measurements conducted at representative C<sub>2</sub>H<sub>4</sub> flames with different equivalence ratios, the accuracies for the measurements of temperature, CO<sub>2</sub> concentrations, and CO concentrations were ∼1.062 %, ∼1.082 %, and ∼1.052 %, respectively. All the measurements illustrate the potential of the system for combustion diagnosis.</div></div>\",\"PeriodicalId\":325,\"journal\":{\"name\":\"Fuel\",\"volume\":\"383 \",\"pages\":\"Article 133782\"},\"PeriodicalIF\":6.7000,\"publicationDate\":\"2024-11-26\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Fuel\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0016236124029314\",\"RegionNum\":1,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"ENERGY & FUELS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Fuel","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0016236124029314","RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ENERGY & FUELS","Score":null,"Total":0}
FDM-assisted OA-CEAS system for simultaneous measurements of temperature, CO2, and CO in flames
A system based on off-axis cavity enhanced absorption spectroscopy (OA-CEAS) integrated with frequency division multiplexing (FDM)-assisted wavelength modulation spectroscopy (WMS) was developed for simultaneous measurements of temperature, CO2, and CO in flames by employing two distributed feedback (DFB) diode lasers at 2.0 µm and 2.3 µm. An integrated cavity with an open-path configuration was made up of two cavity mirrors with a reflectivity of 99.8 %, and an effective optical absorption path length of approximately 5.2 m was achieved within a 6 cm diameter flame region. A CO2 line pair at 4990.418 cm−1 and 4990.664 cm−1, along with a CO line at 4300.699 cm−1, were selected as the measurement targets. The system was initially calibrated in a heated static cell and subsequently tested in C2H4/air premixed flat flames for six different equivalence ratios. All concentrations measured by the 1f-normalized 2f signals were compared with the results obtained from both the direct absorption signals and simulations based on adiabatic chemical equilibrium calculations using Chemkin. Additionally, the measured temperatures were compared with the thermocouple readings. According to the measurements conducted at representative C2H4 flames with different equivalence ratios, the accuracies for the measurements of temperature, CO2 concentrations, and CO concentrations were ∼1.062 %, ∼1.082 %, and ∼1.052 %, respectively. All the measurements illustrate the potential of the system for combustion diagnosis.
期刊介绍:
The exploration of energy sources remains a critical matter of study. For the past nine decades, fuel has consistently held the forefront in primary research efforts within the field of energy science. This area of investigation encompasses a wide range of subjects, with a particular emphasis on emerging concerns like environmental factors and pollution.