Khalid A. Alrashidi , Iram Manzoor , Abdul Ghafoor Abid , Saikh Mohammad , Muhammad Bilal , Nadir Abbas , Farooq Ahmad , Jafar Hussain Shah
{"title":"NdFeO3/rGO 复合材料在增强氧气和氢气进化反应中的协同电化学性能","authors":"Khalid A. Alrashidi , Iram Manzoor , Abdul Ghafoor Abid , Saikh Mohammad , Muhammad Bilal , Nadir Abbas , Farooq Ahmad , Jafar Hussain Shah","doi":"10.1016/j.jelechem.2024.118807","DOIUrl":null,"url":null,"abstract":"<div><div>The research delves into a comprehensive process for synthesizing and characterizing NdFeO<sub>3</sub>, reduced graphene oxide (rGO), and their composite. In present work, the NdFeO<sub>3</sub>/rGO composite is synthesized using ultrasonic methods. Subsequently, techniques such as FT-IR, XRD, SEM, EDX, and XPS univocally affirmed the synthesis of NdFeO<sub>3</sub>/rGO. The pristine materials NdFeO<sub>3</sub>, rGO, and NdFeO<sub>3</sub>/rGO were investigated for oxygen evolution reaction (OER) and hydrogen evolution reaction. The findings reveal that the NdFeO<sub>3</sub>/rGO composite exhibits superior OER and HER compared to individual components in the presence of 1 M KOH solution. The NdFeO<sub>3</sub>/rGO at current densities of 100, 500 and 1000 mAcm<sup>−2</sup> displays lower overpotentials 220, 255 and 345 mV for OER and enhanced stability over extended testing periods for 80 h. Similarly, composite at current densities of 100, 500, and 1000 mAcm<sup>−2</sup> to acquire overpotentials of 206, 301, and 466 mV, respectively. The exalted electrocatalytic performance of NdFeO<sub>3/</sub>rGO is related to the production of synergism between NdFeO<sub>3</sub> and rGO, promoting faster charge transfer kinetics and catalytic activity. Overall, the study underscores the potential of NdFeO<sub>3</sub>/rGO as promising and inexpensive electrocatalysts for OER and HER, offering significant promise for applications in sustainable energy conversion.</div></div>","PeriodicalId":355,"journal":{"name":"Journal of Electroanalytical Chemistry","volume":"976 ","pages":"Article 118807"},"PeriodicalIF":4.1000,"publicationDate":"2024-11-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synergistic electrochemical performance of NdFeO3/rGO composite for enhanced oxygen and hydrogen evolution reactions\",\"authors\":\"Khalid A. Alrashidi , Iram Manzoor , Abdul Ghafoor Abid , Saikh Mohammad , Muhammad Bilal , Nadir Abbas , Farooq Ahmad , Jafar Hussain Shah\",\"doi\":\"10.1016/j.jelechem.2024.118807\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>The research delves into a comprehensive process for synthesizing and characterizing NdFeO<sub>3</sub>, reduced graphene oxide (rGO), and their composite. In present work, the NdFeO<sub>3</sub>/rGO composite is synthesized using ultrasonic methods. Subsequently, techniques such as FT-IR, XRD, SEM, EDX, and XPS univocally affirmed the synthesis of NdFeO<sub>3</sub>/rGO. The pristine materials NdFeO<sub>3</sub>, rGO, and NdFeO<sub>3</sub>/rGO were investigated for oxygen evolution reaction (OER) and hydrogen evolution reaction. The findings reveal that the NdFeO<sub>3</sub>/rGO composite exhibits superior OER and HER compared to individual components in the presence of 1 M KOH solution. The NdFeO<sub>3</sub>/rGO at current densities of 100, 500 and 1000 mAcm<sup>−2</sup> displays lower overpotentials 220, 255 and 345 mV for OER and enhanced stability over extended testing periods for 80 h. Similarly, composite at current densities of 100, 500, and 1000 mAcm<sup>−2</sup> to acquire overpotentials of 206, 301, and 466 mV, respectively. The exalted electrocatalytic performance of NdFeO<sub>3/</sub>rGO is related to the production of synergism between NdFeO<sub>3</sub> and rGO, promoting faster charge transfer kinetics and catalytic activity. Overall, the study underscores the potential of NdFeO<sub>3</sub>/rGO as promising and inexpensive electrocatalysts for OER and HER, offering significant promise for applications in sustainable energy conversion.</div></div>\",\"PeriodicalId\":355,\"journal\":{\"name\":\"Journal of Electroanalytical Chemistry\",\"volume\":\"976 \",\"pages\":\"Article 118807\"},\"PeriodicalIF\":4.1000,\"publicationDate\":\"2024-11-16\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Electroanalytical Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S1572665724007859\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, ANALYTICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Electroanalytical Chemistry","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1572665724007859","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, ANALYTICAL","Score":null,"Total":0}
Synergistic electrochemical performance of NdFeO3/rGO composite for enhanced oxygen and hydrogen evolution reactions
The research delves into a comprehensive process for synthesizing and characterizing NdFeO3, reduced graphene oxide (rGO), and their composite. In present work, the NdFeO3/rGO composite is synthesized using ultrasonic methods. Subsequently, techniques such as FT-IR, XRD, SEM, EDX, and XPS univocally affirmed the synthesis of NdFeO3/rGO. The pristine materials NdFeO3, rGO, and NdFeO3/rGO were investigated for oxygen evolution reaction (OER) and hydrogen evolution reaction. The findings reveal that the NdFeO3/rGO composite exhibits superior OER and HER compared to individual components in the presence of 1 M KOH solution. The NdFeO3/rGO at current densities of 100, 500 and 1000 mAcm−2 displays lower overpotentials 220, 255 and 345 mV for OER and enhanced stability over extended testing periods for 80 h. Similarly, composite at current densities of 100, 500, and 1000 mAcm−2 to acquire overpotentials of 206, 301, and 466 mV, respectively. The exalted electrocatalytic performance of NdFeO3/rGO is related to the production of synergism between NdFeO3 and rGO, promoting faster charge transfer kinetics and catalytic activity. Overall, the study underscores the potential of NdFeO3/rGO as promising and inexpensive electrocatalysts for OER and HER, offering significant promise for applications in sustainable energy conversion.
期刊介绍:
The Journal of Electroanalytical Chemistry is the foremost international journal devoted to the interdisciplinary subject of electrochemistry in all its aspects, theoretical as well as applied.
Electrochemistry is a wide ranging area that is in a state of continuous evolution. Rather than compiling a long list of topics covered by the Journal, the editors would like to draw particular attention to the key issues of novelty, topicality and quality. Papers should present new and interesting electrochemical science in a way that is accessible to the reader. The presentation and discussion should be at a level that is consistent with the international status of the Journal. Reports describing the application of well-established techniques to problems that are essentially technical will not be accepted. Similarly, papers that report observations but fail to provide adequate interpretation will be rejected by the Editors. Papers dealing with technical electrochemistry should be submitted to other specialist journals unless the authors can show that their work provides substantially new insights into electrochemical processes.